research proposal example inorganic chemistry

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Research Proposal Activities in an Advanced Inorganic Chemistry Lecture at the Undergraduate Level

With cutting edge research comes the expectation that funding is needed. Particularly in the sciences, grant funds can cover the cost of instrumentation, conference travel, summer stipends and the like. At the undergraduate level, it is essential to instill into the students the importance of finding and applying to funding opportunities (particularly for those who wish to pursue graduate degrees). While the Georgia College (GC) chemistry program currently does not have a formal "technical writing class", here are discussed several activities that seek to expose undergraduate students to proposal writing and bettering their technical writing skills. La investigación y diseminación de proyectos científicos novedosos requieren fondos monetarios. Particularmente en las ciencias, estos fondos pueden cubrir los costos de instrumentación, viajes a conferencias, estipendios de verano y otros. A nivel pre-doctoral, es esencial inculcar a los estudiantes la importancia de la adquisición de fondos monetarios (particularmente para aquellos estudiantes que desean estudiar a nivel de doctorado). Mientras que el programa de química de Georgia College (GC) no posee un curso de escritura técnica, en este artículo se discuten algunas actividades que exponen a estudiantes pre-doctorales a la escritura de propuestas y el mejoramiento de sus habilidades en escritura técnica. Palabras clave: Escritura de propuestas; química inorgánica avanzada; propuesta investigativa; investigación a nivel pre-doctoral; seminario integrador

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In the case of General Chemistry, many engineering students only take a one semester class with important topics such as kinetics and equilibrium being given limited coverage. Considerable time is spent covering materials already covered in other courses such as General Physics and Introduction to Engineering. Moreover, most GChem courses are oriented toward health science majors and lack a materials focus relevant to engineering. Taking an atoms first approach, we developed and now run a one-semester course in general chemistry for engineers emphasizing relevant materials topics. Laboratory exercises integrate practical examples of materials science enriching the course for engineering students. First-semester calculus and a calculus-based introduction to engineering course are prerequisites, which enables teaching almost all the topics from a traditional two semester GChem course in this new course with advance topics as well. To support this course, an open access textbook in LibreText, formerly ChemWiki was developed entitled General Chemistry for Engineering. Many of the topics were supported using Chemical Excelets and Materials Science Excelets, which are interactive Excel/Calc spreadsheets. The laboratory includes data analysis and interpretation, calibration, error analysis, reactions, kinetics, electrochemistry, and spectrophotometry. To acquaint the students with online collaboration typical of today's technical workplace Google Drive was used for data analysis and report preparation in the laboratory. Updated course website: https://sites.google.com/view/ssinex/home/chm-2000 *************************** A follow-up paper, "Modernizing the Engineering Curriculum: A Community College Approach to Integrate Materials", was published in J. Materials Education 40 (3-4), 125-132 (2018).

35911 Overview of the Research Proposal

Published: August 2008
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In this module, we focus on writing a research proposal, a document written to request financial support for an ongoing or newly conceived research project. Like the journal article (module 1), the proposal is one of the most important and most utilized writing genres in chemistry. Chemists employed in a wide range of disciplines including teaching (high school through university), research and technology, the health professions, and industry all face the challenge of writing proposals to support and sustain their scholarly activities. Before we begin, we remind you that there are many different ways to write a successful proposal”far too many to include in this textbook. Our goal is not to illustrate all the various approaches, but rather to focus on a few basic writing skills that are common to many successful proposals. These basics will get you started, and with practice, you can adapt them to suit your individual needs. After reading this chapter, you should be able to do the following: ◾ Describe different types of funding and funding agencies ◾ Explain the purpose of a Request for Proposals (RFP) ◾ Understand the importance of addressing need, intellectual merit, and broader impacts in a research proposal ◾ Identify the major sections of a research proposal ◾ Identify the main sections of the Project Description Toward the end of the chapter, as part of the Writing on Your Own task, you will identify a topic for the research proposal that you will write as you work through this module. Consistent with the read-analyze-write approach to writing used throughout this textbook, this chapter begins with an excerpt from a research proposal for you to read and analyze. Excerpt 11A is taken from a proposal that competed successfully for a graduate fellowship offered by the Division of Analytical Chemistry of the American Chemical Society (ACS). As is true for nearly all successful proposals, the principal investigator (PI) wrote this proposal in response to a set of instructions. We have included the instructions with the excerpt so that you can see for yourself how closely she followed the proposal guidelines.

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Research Projects at the Institute of Inorganic Chemistry

Research projects of our research groups, research projects: complete list.

Surface interaction and dynamics of molecular spin-probes as guests in tailor-made organosilica, porous hosts for applications in chromatography. Mass transport in, trough and out of porous solids is a deciding factor in a number of applications in process engineering, e.g. chromatography. One has to consider a hierarchical process, spanning several orders of length- and time-scales. At the molecular scale, in the range of few nanometers and picoseconds, there is a complex interplay between guest-solvent and guest-surface interactions, and this determines directly the mobility of those guests inside the porous materials. A comprehensive and scale-spanning, experimentally underpinned understanding of the transport of dissolved molecular species inside (functionalized) porous matrices is pivotal for realizing porous solids designated for particular applications (e.g. chromatography) by design rather than by empiricism. However, it is very difficult to "spot" the confined guests with sufficient temporal and spatial resolution at technically relevant conditions (in the presence of solvents and at T >= r.t.). We have successfully established electron spin resonance (ESR) spectroscopy as an analytical "eye". Now, we will advance the ESR methodology, aiming at more precise and first and foremost scale-spanning insights into the diffusion of molecular spin probes in pores. Furthermore, we are going to establish a direct link between the synthesis of tailor-made, porous materials, which will enable to exert a much more controlled influence on the mass transport of dissolved species. We will dedicate ourselves to the exciting question of effects of spectator groups, which are present in addition to the active components (predominantly taking part in the guest-surface interaction). We expect that the mobility of guest molecules is mainly dependent on the surface density of the active components, but spectator groups may have a significant importance as well due to the local affect on solvent properties, for instance. The required, systematic variations of surface properties will be realized via bifunctional organosilica materials. Due to the high degree of novelty, we anticipate a substantial acquisition of new knowledge from the combination of materials with chemical gradients and imaging ESR spectroscopy. The imaging methodology allows recording the spectroscopic signature of the guests at every position of the porous material. From these data we can obtain information about the local dynamics and mobility, and at the same time one can analyse the mass transport through the porous medium at macroscopic dimensions. The direct correlation between molecular and macroscopic transport will finally enable to investigate the separation of a compound mixture, by means of spectroscopy using two different spin probes and also for the concrete application, a chromatographic measurement. Led by: Professor Dr. Sebastian Polarz Year: 2013 Funding: DFG Duration: 5 Jahre
Materials World Network (MWN) for Particle-mediated Control Over Crystallization: From the Pre-nucleation Stage to the Final Crystal A Materials World Network (MWN) will be formed to investigate mechanisms of particle-mediated crystallization through which mesocrystals — crystals structured on the mesoscale — are created. In biomineral systems, mes-ocrystal formation is a widespread phenomenon mediated by biomolecules and leading to the hierarchical organization commonly associated with these materials. Our ultimate goal is a mechanistic understanding of this process and a set of principles to guide biomimetic strat-egies to create hierarchically organized materials (e.g. bioceramics, photonic solids, energy harvesting materials). The value added by the international collaboration is that it facilitates this goal by combining expertise in chemistry and growth of mesocrystals with capabilities in high-resolution in situ imaging, measurement of interactions, determination of structure, and modeling and simulation from the atomic to mesoscale. Using the calcium carbonate, iron oxide and calcium-silicate hydrate (C-S-H) systems combined with polymers, the project will pursue three thrusts, structured around the key scientific questions: Thrust 1: The pre-nucleation stage, nucleation of primary nanoparticles and intermediate phases - The nature of pre-nucleation clusters will be determined using ion potential measurements, titration and ultracentrifugation. Their solution interaction dynamics will be probed through liquid cell TEM. Thrust 2: Interactions forces between nanocrystals and organic mediators of mesocrystal formation – The interactions responsible for particle co-orientation and reorientation will be determined through a combination of dynamic force spectroscopy (DFS) and modeling. DFS will provide a direct measure of the free energy of the orientation dependent crystal-crystal and -polymer interactions. Experimental measurements are supported by molecular model-ing, which allows us to determine molecular details of the effective interactions and provides parameters for the phase field calculations in Thrust 3. Thrust 3: Post-nucleation particle ag-gregation and co-orientation – The kinetics of particle aggregation, crystallographic orienta-tions of the aggregating particles as a function of time, and structural evolution of mesocrys-talline aggregates will be investigated by liquid cell TEM and ex situ HRTEM. Emphasis will be placed on distinguishing between oriented attachment and orientation following random aggregation either through whole-particle rotation or atomic-scale ripening. These data will be compared to phase-field models of mesocrystal assembly that utilize the interaction energies determined in Thrust 2. Led by: Prof. Dr. H. Cölfen, Prof. Dr. D. Gebauer, Prof. Dr. H. Emmerich Year: 2013 Funding: Deutsche Forschungsgemeinschaft (DFG) Duration: 2013-2017
From birth to growth of metastable metal oxides in ionic liquids It is widely known from chemistry that the energy of transient states may be affected decisively by a surrounding solvent, so is the outcome of a chemical reaction. Also in materials science, one could interpret nanosized seeds as transient states for the generation of shaped particles or of phases with alternative crystal structure. In both cases, one is often interested in thermodynamically less favored (metastable) products, respectively unusual shapes or polymorphs. Besides crystal structure, also shape of a crystal is an important parameter determining its properties. This is, because a particular shape is characterized by a unique set and abundance of surfaces corresponding to different lattice planes. The accession of the mentioned, metastable materials products is linked to the possibility to generate the solid phase under kinetically controlled reaction pathways.The main task of the project is the investigation of the effects in highly polar, non-aqueous solvent environments (ionic liquids) with regards to the formation of metastable products. We will focus on the preparation of anisotropic particles deviating from the most stable shape (Wulff morphology). Furthermore, we are also interested in the role of the solvent concerning accession of metastable crystal structures.We will achieve such kinetically controlled conditions by interfacing molecular routes with materials synthesis, combined with refined in-situ investigations. Highly reactive, organometallic precursors will be used by us for the preparation of important metal oxide semiconductor materials like zinc oxide (ZnO) or manganese oxide (MnxOy). A particular challenge is the generation of novel precursors comprising reluctant groups (e.g. oxidizing and reducing) joined together in one molecule for the purpose of initiating particle growth either at very low temperatures near ambient or below, or initializing it by a non-conventional trigger such as light. A profound base of knowledge will be acquired by us, not only by a detailed analysis of the final materials, but also by comprehensive X-ray scattering investigations (small and wide angle) conducted in an in-situ mode. The advantage of the proposed transition metal oxides is that the contrast in electron density compared to the organic, ionic liquid environment is sufficient for performing scattering with a high tempospatial resolution. We will spot the very early stages of particle formation, raising the question at which point for instance formation of shape and crystal structure is determined. Led by: Professor Dr. Sebastian Polarz, Professor Dr. Bernd Smarsly Year: 2014 Funding: DFG Duration: 4 years
Inorganic surfactants with multifunctional heads Surfactants are molecules of enormous scientific and technological importance, which are widely used as detergents, emulsifiers or for the preparation of diverse nanostructures. Fascinating abilities regarding the formation of self-organized structures, like micelles or liquid crystals, originate from their amphiphilic architecture, which comprises a polar head group linked to a hydrophobic chain. While almost all known surfactants are organic, a new family of surfactants is now emerging, which combine amphiphilic properties with the advanced functionality of transition metal building blocks. The current project aims at the synthesis of unique inorganic surfactants (I-SURFs), which contain multinuclear, charged metal-oxo entities as heads, and their exploration with regard to additional redox, catalytic or magnetic functionalities. A particular challenge is the creation of smart surfactant systems that can be controlled via external stimuli. While thermotropic liquid crystals and their adjustment in electric fields (enabling LCDs) have been studied in depth, very limited research concerns the control of self-assembled amphiphilic structures by use of magnetic fields. It is obvious that exposure to a magnetic field has inherent advantages over electric fields for controlling structures in water. I-SURFs with single-molecule magnets as heads will be thus prepared and studied. Another groundbreaking task is the creation of I-SURFs with additional catalytic activities. Since catalytic heads can be positioned via self-organization, for instance on the surface of micellar aggregates, catalytic relay systems can be assembled with a second catalytic species in proximity to the first. Thus, cooperative effects in catalytic tandem reactions will ultimately be observed. These examples show that frontier research on I-SURFs is of outstanding relevance for supramolecular science and will certainly pave the way toward new technological applications with great benefits to society. Led by: Professor Dr. Sebastian Polarz Year: 2014 Funding: ERC Duration: 5 Jahre
Advanced Hybrids of Calcium Carbonate and Nanocellulose Led by: Prof. Dr. D. Gebauer Team: Prof. Dr. L. Bergström Year: 2014 Funding: Baden-Württemberg Stiftung (Stuttgart) Duration: 2014-2017
Morphosynthesis of ceramic semiconductor and ferroelectric nanocrystals For particle-based materials composed of defined nanocrystals, the ability to adjust the properties of the building blocks is vital. Such tuning can be achieved, when the shape gets correlated to the intrinsic anisotropy of the crystallographic system. For this purpose special additives with surfactant design will be synthesized and tailored for the interaction with inorganic surfaces. They will be used during the morphosynthesis of oxidic and non-oxidic semiconductor materials with ferroelectric characteristics. Furthermore, we aim at customizing the electronic properties of the particles via doping while preserving shape control. Led by: Prof. Dr. Sebastian Polarz Year: 2016 Funding: DFG
Shape dependent properties of anisotropic magnetic particles The goal of the project is an understanding of how far the properties of magnetic, nanoscaled particles relate to their crystal shape. We will explore ensembles of tailored nanoparticles of ferro-, ferri- and antiferromagnetic magnetic oxides. A joint effort will be used, combining the synthesis of particles with well-defined morphologies with state-of-the-art analytical methods and accompanying computer simulations to reveal the expected complex spin structures. We aim for the development of novel magnetic materials on the basis of the morphology of the underlying nanoparticles. Year: 2016 Funding: DFG
PAC: Particle Analysis Center In addition to the synthesis of shape-anisotropic nanoparticles, done in the individual projects, their precise characterization and, where appropriate, purification with regards to size or shape distribution is of pivotal importance for the CRC as a whole. The particle analysis center bundles the experience in particle characterization and fractionation. Different methods (including PXRD, SAXS, AUC, light scattering and prep. Ultracentrifugation) will be used and allocated to the scientists of the entire CRC. Led by: Professor Dr. Sebastian Polarz Year: 2016 Funding: DFG
The onset of anisotropy during calcium carbonate and phosphate mineralization Calcium carbonate and phosphate behave very distinctly during the early stages of precipitation, especially regarding the earliest development of morphological anisotropy. In this project, time-resolved in situ analyses of precipitation are designed to elucidate the underlying key factors. The goal is to enable a better understanding of the control of polymorphism and morphology of crystals, so as to pave the way to the rational generation of colloidal building blocks. Led by: Prof. Dr. D. Gebauer and Prof. Dr. K. Hauser Year: 2016 Funding: DFG
A07: Bifunctional hybrid nanoparticles via calcium carbonate crystallization driven by engineered protein surfaces This project aims at the defined generation of structurally and functionally anisotropic nanohybrid particles of calcium carbonate and tailor-made genetically engineered proteins via non-classical pathways of crystallization. Iterative cycles of protein design and thorough investigations of their effect on in vitro calcium carbonate precipitation will identify the essential factors underlying this complex process. Eventually, this will pave the way for the rational generation of particle superstructures via directed self-assembly. Led by: Prof. Dr. D. Gebauer, Prof. Dr. A. Marx Year: 2016 Funding: DFG
Control of crystallisation in minerals This project aims to increase our knowledge of the processes of mineral formation and crystallisation. Minerals play a vital role in our environment, for example as reservoirs for carbon dioxide, while also substantially contributing to the Australian economy. Conversely, undesirable formation of minerals can be detrimental to industries from the oil/gas sector through to desalination. Despite the benefits that would come from controlling such crystal growth, progress has been limited by the lack of a complete understanding of how minerals form at the microscopic level. This project aims to combine computer simulation, using the latest petascale resources, with experimental data to yield knowledge that would allow us to manipulate minerals, such as calcium carbonate, with the same control found in nature. Led by: Prof. Dr. J. D. Gale Team: Dr. R. Demichelis, Prof. Dr. D. Gebauer, Prof. Dr. C. Putnis Year: 2016 Funding: Australian Research Council Duration: 2016-2019
Functional interfacial additives as energy valves in particle-based gradient structures made of organic-inorganic perovskite phases Recently, so-called hybrid perovskites such as CH3NH3PbX3 (X = Hal) have moved into the focus of international research because of their extraordinary semiconductor properties. A special feature is, the band-gap can be adjusted precisely by substitution in the anion lattice. The band-gap also depends on the extension of perovskite layers. One then speaks of Ruddlesden-Popper phases (RPPs), in which an organic phase has become an integral part of the crystal, a phenomenon unlike to other semiconductors. This makes the design of the internal and external interfaces highly important for RPPs. RPPs are established and well-investigated for alkyl ammonium compounds as interfacial additives. However, because of the electrically insulating character one is interested to advance to functional interfacial additives (FIAs). This is, where we begin. The proposed research project comprises the organic synthesis of new FGAs and their utilization for the preparation of RPP microparticles. For the direct interaction with the perovskite surfaces the FGAs carry a cationic head-group, attached to a -conjugated side chain. In addition, we aim at implementing photo-switchable groups, and the corresponding FGAs should be established as energy valves. The systems should now be developed further in work package 1 based on our successful, preliminary work on single-source precursors for hybrid perovskites, as well as on thiophene- and azobenzene-based FGAs. In work package 2, the generation of the microparticles is done in combination with single-particle studies, which represent ideal models for understanding the ensemble situation. We will finally (work package 3) assemble microparticles possessing a different band-gap into multi-junction architectures with gradient character. This should lead to energy cascades in the resulting particle-based materials. The work packages are accompanied by extensive photophysical measurements for determining and quantification of the intra-particle and inter-particle energy transfer mechanisms. Led by: Professor Dr. Sebastian Polarz Year: 2018 Funding: DFG
Point-Defect Design and Facet-Selective Optoelectronic Properties in Doped Perovskite Microcrystals Type and density of defects significantly affect the properties and function of a semiconductor leading to enhanced or reduced performance. The application in photovoltaics or in optoelectronics requires in-depth knowledge of defect-property relationships. This aspect is more prevailing for hybrid lead-halide perovskites, in which a high defect density exists due to relatively low cohesion energy of these solution-processed solids. The resulting films exhibit a broad range of defects such as various point-defects (vacancies, interstitials or heteroatoms), but also interfaces between phases within the perovskite or with charge injection/extraction materials (2-D defects) are relevant. Metal-halide perovskites show surprising tolerance to defects, nevertheless, non-radiative recombination is still the major loss channel and needs to be minimized to optimize device operation. Systematic investigations are aggravated by the complexity of hybrid perovskites and the technological need for sustainable, solution-based fabrication. Model systems are needed to answer questions about the limits and placing of defects in the lattice, and how their interplay determine associated electrical and photophysical properties. The generation of a specific defect architecture has not been achieved to enable, for example, controlled doping. The project brings together expertise in chemical synthesis (Polarz), physics of semiconductor nanostructures (Schmidt-Mende) and spatially resolved electronic and optoelectronic measurements (Weber, Deschler) to tackle following tasks: (i) aerosol synthesis of MAPX (CH3NH3PbX3); (ii) role of crystal direction and facets on optical and electronic properties; (iii) role of controlled dopant concentration (stoichiometry), (iv) advanced functionalization of MAPX by inclusion of new dopants. We apply a gas-phase based method, which generates highly crystalline and differently faceted microcrystals from special liquid single-source precursors. The precursor acts also as solvent, which allows us to dissolve heteroelements in the aerosol droplets for the controlled introduction of point-defects. The advantage of micropartices deposited on any desired substrate is, one can probe individual crystals, orientation and facets. We will apply techniques like conductive atomic force microscopy (C-AFM) and time-resolved Kelvin probe spectroscopy for clarification how the stoichiometry, presence of dopants and defects influence the local electrical and ionic conductivity. The effect of ferroelastic domains will be investigated on a single-particle level as well using piezoresponse force microscopy (PFM). Our understanding of electronic properties of defect-property correlations will be complemented by spectroscopic measurements on the photophysics of the defect-doped systems, with high-resolution photoluminescence microscopy, which is a unique method to resolve dynamical processes and radiative recombination on the relevant ultrafast time-scales. Led by: Professor Dr. Sebastian Polarz,Professor Dr. Lukas Schmidt-Mende, Ph.D., Professor Dr. Stefan Weber Year: 2019 Funding: DFG
The influence of supramolecular directors bound to surfaces of porous hosts with chiral walls on the dynamic of enantiomers as guests An important application of porous solids is for separation of (similar) chemical compounds by chromatography. Enantiomers represent the case of ultimate similarity between molecules and, thus, purification is in general demanding. Chromatographic separation also relies on statistics, a high number of contacts of the dissolved guest species with the surfaces via diffusion ensures, some events occur in proper orientation to induce stereochemical differentiation in intermolecular interaction. Maximum mobility discrimination of the enantiomers to be separated with a minimum amount of a chiral selector necessary at the surfaces of the solid phase is desired. For the identification of new concepts in stereoselective chromatography, it is helpful referring to a different area, asymmetric catalysis. There, the sole presence of a chiral ligand is not enough for achieving best enantiomeric excess. A precise control over the orientation of the starting compounds towards the active center is pivotal. The transfer of the latter concept to host-guest chemistry in porous materials leads to our long-term vision: The design of surfaces to become capable of orienting chiral guests for maximizing the effect on their mobility and reaching optimum enantioselective separation. For the target-oriented synthesis of such a complex host material, one has to be able to watch separation with molecular precision and quantify the molecular dynamics and mobility of guests confined to the pores of the material close to chromatographic process conditions. Our group has shown in preliminary work, this is possible using electron spin resonance spectroscopy (ESR) techniques. The methodology is now developed sufficiently, it can be applied to gather detailed information about separation using chiral, amino-acid modified organosilica materials as model systems. Our first work-package is concerned with gaining control over confinement conditions. We present new templating approaches for the synthesis of organosilica materials with narrow size distribution of pores in the 50-150 nm range. A systematic variation of the interaction of chiral nitroxides as paramagnetic spin-probes with the surfaces is realized in the second work-package. A particularly interesting question is, how non-chiral neighboring groups on the surface can influence the separation process and ultimately act as supramolecular directors for orienting the nitroxide guests in a specific way. Our main observable is the enantiomer selectivity factor alphaT obtained from cw-ESR experiments, and also coefficients for nanoscopic and macroscopic transport will be determined, for instance from imaging ESR spectroscopy. Finally, we want to perform a HPLC separation experiment using a monolithic organosilica material, to learn how the fundamental host-guest study translate to application. Led by: Professor Dr. Sebastian Polarz Year: 2019 Funding: DFG

Cooperative effects for carbon dioxide capture in nanoporous, bifunctional organosilica materials Atmospheric carbon dioxide (CO2) is an example for a plentifully available waste product. The chemical conversion of waste products into valuable compounds is highly desirable, in particular when no significant amounts of energy or other resources are consumed. The first necessary conversion step is the fixation of CO2 from the gas-phase. Sustainability is hardly realized considering the currently applied wet process, the so-called amine washing. Thus, numerous scientists became interested in developing solid adsorbents for carbon capture applications. The interplay between CO2 capture and release, the latter being required for succeeding process steps and the regeneration of the material, makes fine-tuning of the adsorption enthalpy desirable. Nanoporous silica materials with surfaces containing primary amines have already been demonstrated to be promising. However, the literature discusses almost exclusively mono-functional materials comprising only one single (amine) moiety. Here starts the current project. We want to understand, how the CO2 adsorption properties of a nanoporous material change, when an additional moiety is present on its surface in direct vicinity to the amine group. Such neighboring group effects have been described in only few papers, but a systematic, experimental study is missing. Half of the project is focused on materials synthesis providing bifunctional organosilica aerogels with monolithic shape. Close collaboration takes place with the physical chemistry part of the project, which analyzes the adsorption behavior using (T-dependent) volumetric methods as well as spectroscopic methods, most importantly infrared (IR)-spectroscopy including spatially resolved techniques. We expect that uptake capacities, adsorption enthalpies and kinetic data enable us to identify which neighboring group leads to strong interaction effects and why. After identification of promising combinations among amine- and neighboring groups, another parameter space opens up, namely the relative abundance of both moieties to each other. We will examine this parameter space by exploiting new materials characterized by chemical gradients, in which the density of one constituent systematically varies along one spatial coordinate. The anisotropic modification of the monoliths using click chemistry (azide-alkyne; thiol-alkene) will be applied for synthesizing the gradient materials. The uptake of CO2 can then be studied at different positions of the gradient materials using IR microscopy. The existence of a gradient material shall open new research possibilities, for instance for studying anisotropic and directional transport in the material. Led by: Professorin Dr. Karin Hauser and Professor Dr. Sebastian Polarz Year: 2020 Funding: DFG
Hierarchical Nanomaterials with Biological Functions for Anti-Biofilm Applications and Localized Toxicity Led by: Professor Dr. Sebastian Polarz Year: 2020 Funding: Dr. K. H. Eberle Foundation
New functional materials with directional porosity structure. Led by: Professor Dr. Sebastian Polarz Year: 2020 Funding: Carl-Zeiss Foundation
Sustainable synthesis of thin films for energy technology Led by: Professor Dr. Sebastian Polarz Year: 2020 Funding: Carl-Zeiss Foundation
Porous supercrystals via biomimetic structure formation processes of polar nanocrystals and their applications in efficient solar cells. Led by: Professor Dr. Sebastian Polarz Year: 2020 Funding: Baden-Württemberg Foundation
Porous materials for storing chlorine Led by: Professor Dr. Sebastian Polarz Year: 2020 Funding: Covestro AG
Control of nucleation and crystallization of Al(III)(oxy)(hydr)oxides: An avenue toward advanced materials Led by: Prof. Dr. D. Gebauer Year: 2021 Funding: DFG

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Organic Reaction Mechanisms

Try filling out this template to make sure you’re on track: Key Elements of a Proposal Example

The Topic 1. Ideally, the proposal should take advantage of fundamental principles from a graduate course(s) you are taking this quarter: e.g., Chem 201 Organic Reaction Mechanisms, Chem 215 Inorganic Chemistry, Chem 216 Organometallic Chemistry, Chem 223 Biomacromolecules. 2. Don’t propose things that others are already working on. 3. Don’t propose things you’ve already done, like your undergraduate research project. Proposals in related areas of research would be OK.

Your Proposal Proposals are due in class on Friday, October 21. Feel free to use your proposal for grant applications such as the NSF Graduate Fellowship (due October 28). • maximum length of two pages, including all references, citations, charts, figures, and images. • standard 8.5″ x 11″ page size, 1″ margins on all sides •12-point, Times New Roman font, single spaced. • Only references and footnotes may be a smaller font, no less than 10- point Times New Roman. • Chemdraw structures should be ACS standard settings, pasted at 75% size (not smaller!)

Take advantage of Dr. Lori Greene’s workshops: Drop-in essay editing with past awardees. Tuesday from 4-6 pm

Other Resources: Chemistry conventions, use of italics, referencing, etc: ACS style guide Grammar, paragraph structure, etc: Strunk and White Scientific writing: http://www.amazon.com/Scientific-Writing-Communication-Proposals-Presentations/dp/0199947562

Inorganic Chemistry

Inorganic chemistry is no longer just the chemistry of metallurgy and mineralogy, or even the "everything else except carbon" discipline.

Inorganic chemistry is better explained as a loose identity for chemists with research interests that span the periodic table. Modern inorganic chemistry is an exciting undertaking, embracing a range of rapidly evolving interdisciplinary fields. At the University of Iowa, inorganic research interests encompass many interdisciplinary topics including biological, environmental, radiochemistry, materials and catalysis, and organometallics.

Inorganic chemistry faculty

Korey Carter

Scott R. Daly

Tori Z. Forbes

Edward G. Gillan

Lou Messerle

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Department of Chemistry

Chemistry REU Program

Proposed research projects.

(Note that not all research projects and groups are available each summer. The list found here is to give a general idea of the program’s offering.)

Polymer Based Vesicles for Therapeutics Dr. Douglas Adamson (Polymer Chemistry)

Mechanistic Inorganic Chemistry Dr. Alfredo Angeles-Boza (Inorganic Chemistry)

We use synthetic chemistry, both organic and inorganic, as a tool to design and build new molecules for targeted applications. We are particularly interested in the social dilemmas of climate change and antibiotic resistance. Interestingly, both problems can be thought as examples of tragedies of the commons.

Our current research efforts are centered in two key areas: 1) Development of novel catalysts for the activation of small molecules (CO 2 , O 2 , H 2 O). We synthesize new catalysts and study their activity with a focus on kinetics and reaction mechanisms. We are one of the few groups in the world that use of heavy atom isotope effects to study reaction mechanisms. 2) Design and synthesis of compounds with medicinal properties that take advantage of the important role of metal ions in biological systems. Our approach involves synthesizing novel molecules and characterizing them with an arsenal of physical, chemical and spectroscopic data. In recent years, we have focused on the synthesis of peptides and peptidomimetics. Angeles-Boza Group Website

Use of Persistent Radical Catalysts in Living Polymerization Reactions Dr. Alexandru Asandei (Polymer Chemistry)

Synthesis and Study of DNA Damages Dr. Ashis K. Basu (Bioorganic Chemistry)

We study chemicals and drugs that exert their biological effects through DNA damage. Some of the chemicals are environmental pollutants such as 1–nitropyrene. We also study ionizing radiation-induced DNA damages. The REU student will synthesize a specific DNA damage such as a DNA adduct of a nitroaromatic compound or induce an ionizing radiation damage into a designed oligo¬deoxy¬nucleotide. These DNA lesions can induce mutations which may represent the first step converting a normal cell into a cancer cell. Our goal is to correlate the type of mutation with three dimensional architectural effects induced in DNA. The modified DNA fragments will be used to study mutagenesis and DNA repair. The project will introduce the REU student to a variety of organic synthesis and nucleic acid chemistry tools, chromatography, and structural characterization (NMR, UV-Vis, MS), and introduce the student to molecular biology and recombinant DNA techniques. Basu Web Site

Synthesis of Pyrrole-Modified Porphyrins Dr. Christian Brueckner (Organic Chemistry)

Photodynamic therapy (PDT) employs the combination of a photosensitizer, such as a porphyrin, and light to destroy diseased cells. For PDT to be most effective, the light that activates the drug must penetrate deep into tissue. However, while tissue is only transparent for red and infrared light, porphyrins cannot be activated using red light. Thus, our group has set out a program to modify synthetic porphyrins in a way that they can become photosensitizers which can be activated with red light. Although porphyrins are ubiquitous naturally occurring macrocycles, the regio-selective modification of them can be difficult. Hence, synthetic compounds are needed.

We modify a class sof symmetric meso-aryl-substituted porphyrins by formally replacing one pyrrole by a different heterocycle. One reaction sequence involves the cleavage of the ß,ß’-bond (1 to 2), followed by ring-closure to, in this example, form morpholine-derived porphyrin 3. Oxazole-, imidazole, and pyrazole-based systems are also available along this route.

The REU student will do multi-step syntheses (1-4 steps), purification (column and preparative thin layer chromatography) and characterization (UV-vis, IR, fluorescence spectroscopy, NMR) of porphyrins and metalloporphyrins (NiII, ZnII, AgII). The student will learn many analytic and synthetic techniques employed in modern organic and coordination chemistry. Brueckner Group Web Site

Modeling the Mechanisms of Light Harvesting in a Photosynthetic Antenna Protein Dr. Jose Gascon (Physical and Computational Chemistry)

Gascon Group Web Site

Automated Continuous Flow Chemistries Dr. Kerry Gilmore (Organic Chemistry)

The use of technology in chemistry allows for significant improvements in how we can study and synthesize small molecules. Most notably, the use of continuous flow techniques allows us to perform operations in a safer – and far greener – manner. This technique can be used in a wide breadth of applications, ranging from photo- and electrochemistry for more sustainable production, mechanistic studies to better understand how and why reactions occur, and the synthesis of active pharmaceutical ingredients. Coupled with machine learning, our group uses these approaches to develop better ways of making molecules and accessing previously unexplored areas of chemical synthesis. Critically, these instruments and tools need to be more broadly available, such that the entire chemical community can benefit without having to buy or build things themselves. Akin to cloud computing, we are building a network of automated instruments to perform chemical reactions – this involves writing software, automation/robotics, building new platforms, analytics, and running chemical reactions. We are looking for REU students interested in any of these areas, and those with any experience in coding/robotics are especially welcome to apply. Gilmore group website

Hybrid Materials Dr. Jie (Jay) He (Polymer Chemistry and Physical Chemistry)

Amphiphilic molecules such as liquids, surfactants, and amphiphilic block copolymers can spontaneously form a wide range of nano- or microstructures such as spherical micelles, cylindrical or worm-like micelles, or bilayer vesicles in selective solvents. Analogues to the self-assembly behaviors of atoms or molecules, the self-assembly of colloidal building blocks,so-called “colloidal molecules”, into various supra-architectures or ordered ensembles provides new opportunities to engineering structures and devices with unique optical, magnetic, or electronic properties. Our group is interested in design and synthesis of colloidal molecules and the use of colloidal molecules as model systems to understand atomic or molecular interactions in self-assembly or crystallization. The REU student will be trained with various living polymerization techniques (ATRP and RAFT polymerization) and characterization tools (NMR, GPC and electronic microscopes). The student will be exposed to the synthesis and self-assembly of various nanomaterials.

He Group Web Site

Shape-Memory Polymers Dr. Rajeswari M. Kasi (Polymer Chemistry)

We seek to synthesize, characterize, and, thereby, achieve a fundamental understanding of new biocompatible stimuli-responsive polymers. Development of new synthetic methodologies, modification of existing synthetic routes, multidisciplinary approach to structure-property evaluation, and advanced characterization tools are the overriding factors to rational material design. Shape memory polymers are a class of responsive polymers that show a reversible temporary shape change with temperature. Upon temperature reduction the initial or permanent shape is achieved once again. We are interested in exploring the influence of architecture and states of matter on shape memory application. The triggering temperature used for these applications could be the glass transition, melting or liquid crystalline transition temperature leading to a multi-variable shape memory approach, Figure 1. Shape memory polymers and hybrid structures can be used in drug delivery, tissue engineering scaffolds, artificial muscles, and actuators.

The undergraduate student researcher will be mentored by a graduate student and the faculty member. The student will learn synthetic polymer chemistry methods and characterization techniques to investigate stimuli-responsive and shape memory properties. Kasi Group Web Site

Synthesis and characterization of photoswitchable inhibitors of potassium channels Dr. Michael Kienzler (Organic and Biological Chemistry)

Potassium channels are essential proteins for maintaining excitable cells’ membrane potential, perhaps best known for their role in neuron action potential firing. New molecular tools are needed to interrogate the function of potassium channels with high spatiotemporal precision. Our lab is interested in synthesizing small, photoswitchable molecules that can be used to control protein function, and in this project in particular, potassium channel blockers that can be turned “on” and “off” with different wavelengths of light. To achieve this goal, our photoswitch of choice is azobenzene, which can isomerize between cis and trans forms by irradiating the molecule with different wavelengths of light in the Ultraviolet/visible range.

The REU student will synthesize a series of azobenzene-based photoswitchable inhibitors of potassium channels (2-5 steps), purifying (via column chromatography and HPLC) and characterizing (NMR, Mass Spec) their compounds as they go. The photochemical properties of the final compounds will also be determined (UV/vis spectroscopy, NMR).

From the Kitchen to the Lab Dr. Nicholas Leadbeater (Inorganic Chemistry)

We all know that microwave ovens can be used for heating food fast. An exciting area of study in the synthetic chemistry community is the use of microwaves for making molecules rapidly, easily and cleanly. Using microwave heating, it is possible to enhance the rate of chemical reactions significantly and to do chemistry that was otherwise not possible. Unlike the microwave at home, we use state-of-the-art scientific microwave systems that allow precise control of reaction conditions. One limitation at the moment is the scale-up of reactions to make multi-gram or kilo quantities of compounds. However, we are about to receive a microwave apparatus that is designed to overcome this hurdle. As an REU student, you would play an important role in using this apparatus over the summer and would have your own mini-project focused around the use of microwave heating for scaling-up reactions. You will be mentored by a graduate student in the group. The reactions will be performed in water as a solvent rather than organic solvents thus making the chemistry more environmentally friendly. As well as being exciting, the project will introduce you to a range of modern synthetic chemistry techniques as well as analysis methods. Leadbeater Group Web Site

Supramolecular Assembly of Polypeptides into Nanomaterials Dr. Yao Lin (Polymer Chemistry)

Control of photo-generated charge-separated states in donor-bridge-acceptor molecules dr. tomoyasu mani (physical chemistry).

Research in the Mani Group focuses on photo- and radiation-induced fundamental chemical reactions in the condensed phase. We are particularly interested in controlling electronic excited states, charge and exciton transfer reactions, and spin dynamics in molecules and molecular assemblies. The fundamental understanding of these phenomena will help us improve and develop energy and biomedical technologies.

The REU student will work on the projects that examine the way(s) to control photo-generated charge-separated states. Students will have an opportunity to do either or both organic synthesis and optical (both steady-state and time-resolved) spectroscopy experiments.

Mani Group Web Site

Nanoscale Controlled Light Emitting Devices by Self-Assembly Techniques Dr. Fotios Papadimitrakopoulos (Polymer Chemistry)

Implantable biosensors could be a plausible way to continuously monitor blood glucose levels, provided they exhibit long-term stability and means to establish telemetry. However, their potential applications remain largely unexploited due to the negative tissue responses such as biofouling, inflammation, tissue fibrosis, and calcification generated by the implantation of such devices. Other problems such as electrical short, signal drifts and need for continuous calibration can lead to device malfunctioning and eventually failure. Also, one of the chief concerns is the possibility of sensor breakdown because of oxidative degradation of enzyme and other electrode coatings due to excess of hydrogen peroxide present in the immediate vicinity of the sensing electrode. This is a direct result of over-sampling of the glucose in the blood stream. Coating the device by a biocompatible, semipermeable membrane can rectify this situation. Apart from acting as a barrier to permeation of glucose, the membrane would protect the sensor from foreign molecules that cause fouling. Our group investigated the simplistic, yet versatile approach of layer-by-layer (LBL) self-assembly of assembly of Humic Acids (Has), a naturally occurring biopolymer and Fe3+ cations. Not only did these coatings provide the required degree of glucose permeability, but in vivo results indicated their biocompatibility with reduced tissue fibrosis upon implantation. Furthermore, the conformation and growth characteristics of the HAs/Fe3+ membrane could be tailored by carefully adjusting the pH of the aqueous medium. Apart from the HAs/Fe3+ bilayers, we self-assembled films of HAs/poly (diallyldimethylammonium chloride) (PDDA) and also films of poly (styrene sulfonate) (PSS)/PDDA onto the sensory device. Moreover the diffusion coefficients of glucose through these membrane systems were investigated in order to explain the individual sensor response as it pertains to the microstructure of these outer semipermeable membranes. The hysterisis behavior of these sensors was studied as a function of permeability of the outer membrane. It was concluded that the microstructure of these coatings govern the permeability of glucose and correspondingly, the sensitivity, longevity and hysterisis of the sensors. We plan to extend this outer membrane research to a more biocompatible polyelectrolytes like poly saccharides and proteins, which we aniticipate to finish within one summer.

The incoming REU student will be exposed to a variety of techniques including electrochemical sensor fabrication, electro-analytical techniques, ellipsometry, enzyme immobilization, electropolymerization of conducting polymers, layer by layer assembly, in vitro and in vivo testing of electrochemical sensors as well diffusional based theoretical modeling of electrochemical sensors. Papadim. Group Web Site

Synthesis as a Tool in Glycoscience Dr. Mark W. Peczuh (Organic Chemistry)

Carbohydrates are indispensable to biological processes such as metabolism, protein folding, and cell-cell interactions. Our group is interested in the design, synthesis, and characterization (conformation, binding) of ring expanded carbohydrates that can interact with natural proteins such as lectins and glycosidases. The preparation of novel ligands of these two broad groups of carbohydrate binding proteins may provide new tools for glycobiology or even future drug leads.

The REU student will synthesize septanose carbohydrate glycosides and glycoconjugates designed for their ability to bind natural lectins and glycosidases. The routes for their synthesis will rely on established procedures, or will be developed by the student. They will be multistep sequences (4-6 steps), where compound purification (chromatography, crystallization) and spectroscopic characterization (NMR, IR, CD, MS) are critical aspects of the research. Peczuh Group Web Site

Building Functional Nanodevices with Porous Nanocapsules Dr. Eugene Pinkhassik (Materials/Organic/Analytical/Nanoscience)

Our research group designs functional nanomaterials and devices with new and superior properties to address global challenges in energy-related technologies, sensing, and medical imaging and treatment. We have developed a directed assembly method for the synthesis of vesicle-templated nanocapsules. These nanocapsules offer a unique combination of properties enabled by robust shells with the single-nanometer thickness containing programmed uniform pores capable of fast and selective mass transfer. Vesicle-templated nanocapsules emerged as a versatile platform for creating functional devices, such as nanoreactors, nanosensors, and containers for drug delivery.

The REU student will learn an array of synthetic and analytical techniques ranging from the synthesis of polymer nanocapsules, using self-assembled structures to direct organic synthesis, characterizing nanoscale objects with light scattering and electron microscopy, and evaluating the performance of newly created nanodevices with spectroscopic and chromatographic methods. Having mastered the synthesis of nanocapsules, the REU student will use the capsules to build nanodevices aiming at one of the following applications: nanoreactors with encapsulated homogeneous or enzymatic catalysts, highly selective nanoprobes, containers for the delivery of drugs or imaging agents, or cell-mimicking devices capable of through-shell communication.

Pinkhassik Group Web site

Reliability and Engineering of Molecules and Materials Next-generation Electronics. Dr. Rebecca Quardokus (physical/materials/nanoscience)

The Quardokus group focuses on the reliability and engineering of molecules and new materials for next-generation electronics. Scanning tunneling microscopy (STM), with its ability to image individual atoms and molecules, is the primary tool used to investigate surface-confined molecular interactions and two-dimensional materials. The systems of interest include self-assembled monolayers, two-dimensional polymers, surface-confined reactions, hierarchical designs, and surface-confined molecular rotors and switches. Quardokus Group Web Site

Enzyme-assembled Nanocapsules for Targeted Drug Delivery Dr. Jessica Rouge (Biological Chemistry)

We seek to design, synthesize and characterize nanomaterials that can target specific cell types for the delivery of therapeutic nucleic acids and small molecule drugs.

Nanomaterials have revolutionized the way drugs can be delivered thanks to their small size and enhanced chemical stability. However the ability to direct them to specific cellular targets and to control the release of their therapeutic cargo has been a major obstacle in the field. Our lab seeks to develop new materials that can direct the localization of a nanomaterial to specific cell receptors through the use of DNA aptamers. Aptamers are DNA and RNA sequences that strongly bind specific cellular locations or proteins. We are also interested in controlling the release of the nanomaterials contents through interactions with specific enzymes (esterases). We work to synthesize new substrates that can direct enzymes to the surface of nanomaterials in order to facilitate the enzyme-mediated assembly of chemically modified aptamers to particle surfaces along with the degradation of the nanomaterials itself.

An undergraduate researcher will be exposed to a highly interdisciplinary lab environment, being trained by both a graduate student and the faculty member. The students will learn both chemical and biochemical techniques such as nanoparticle synthesis, automated DNA synthesis, HPLC, PCR, RNA transcription and other enzymatic reactions. Rouge Group Web Site

Cancer Biomarker Detection by Immunoarrays Dr. James F. Rusling (Analytical, Physical Chemistry)

The student will develop analytical protocols for these analyses in serum samples, and attempt to improve sensitivity, detection limit and reproducibility compared to our existing arrays. The student will learn state-of-the-art biomedical sensor preparation technology utilizing nanoparticles and ink-jet biomolecule spotting. The student will also gain experience in electrochemical, AFM and spectroscopic analyses to monitor array fabrication, and the use amperometry for biomarker detection with the microfluidic arrays. Rusling Group Web Site

Catalysts, Ceramics, Batteries, and Adsorbents Dr. Steven L. Suib (Inorganic Chemistry)

Departments of chemistry, chemical engineering, and materials science and engineering, and institute of materials science..

Our NSF funded research program involves the preparation of aligned crystallites on solid surfaces that can be used as Catalysts, Ceramics, Batteries, and Adsorbents. Much of this research involves synthesis of novel metal oxide and sulfide materials that are densely packed but accessible to chemical reagents for distinct chemical and physical reactions.

Figure 1, Diagram of Oriented Fibers; Synthesis, Scanning Electron Micrograph and Coated Product.

Figure 1 above shows a diagram of one of the synthetic processes that is used to make such oriented crystallites. These nano-sized materials are shown to be well aligned in the scanning electron micrograph shown above. The photograph on the right in Figure 1 is that of an uncoated (cream color) cordierite monolith like that in an auto exhaust system in cars and the coated (dark brown) honeycomb support with aligned crystallites. A major advantage of the alignment is that more accessible sites are available for whatever the specific application might be.

For example, the materials in Figure 1 are being studied as auto exhaust catalysts and have shown excellent activity and stability in the oxidation of CO and the reduction of NO x . the same types of oriented materials can enhance the capacity of battery materials, and increase the amount of adsorption for example of extracting harmful sulfur and nitrogen species from a variety of fuels. Many of these materials act as ceramic systems that are stable at very high (> 500 o C) temperatures.

The type of research that would be done under an REU summer program would involve any aspect of synthesis, characterization, or applications of such oriented materials. Related goals of this research program involve use of green reagents, regeneration and sustainability of systems, and scale-up of materials and processes.

References.

Chen, S. Y.; Song, W.; Lin, H. J.; Wang, S.; Biswas, S.; Mollahosseini, M.; Kuo, C. H.; Gao, P. X.; Suib, S. L.; Manganese Oxide Nano-Array Based Monolithic Catalysts: Tunable Morphology and High Efficiency for CO Oxidation, ACS Appl. Mat. & Int ., 2016, 8 , 7834-7842.

Dutta, B.; Biswas, S.; Sharma, V.; Savage, N. O.; Alpay, S. P.; Suib, S. L., Mesoporous Manganese Oxide Catalyzed Aerobic Oxidative Coupling of Anilines to Aromatic Azo Compounds, Ang. Chem. Int. Ed ., 2016, 55 , 2171-2175.

Synthesis of molecules emitting chiral light Dr. Gaël Ung (Inorganic/organic)

Circularly polarized luminescence (CPL) is the preferential emission of light with a certain circular polarization. Upon non-polarized light absorption, a chiral molecule reaches a preferential excited state which radiatively decays by emitting circularly polarized photons. CPL has emerged as a next-generation light source since the added chiral optical information presents unique opportunities to enhance optical displays, bio-imaging, and security f eatures for banknotes and identification documents. The REU student will synthesize chiral and enantiopure ligands, and study their coordination to lanthanides. The complexes obtained should exhibit CPL. Our laboratory is equipped with two rare CPL spectrometers, including the only NIR-CPL in the Americas. The REU student will be trained in a large variety of synthetic techniques (bench top, Schlenk, glove box), as well as spectroscopic characterizations (NMR, UV-vis, IR, EPR, CPL).

Ung Group Web Site

Mass Spectrometry to Investigate Micro-Scale Preparation of Peptide Samples Dr. Xudong Yao (Analytical Chemistry and Biological Chemistry)

Mass spectrometry is used as a fast and sensitive tool to study peptides. Mass spectrometry analyzes charge-to-mass ratios of peptide ions in gas phase. A mass spectrum plots the intensities of ions against their charge-to-mass ratios. These ratios can be used to determine chemical structures of peptides, while the intensities give relative quantitation of the ions. Sample preparation of peptides is a key step for successful mass spectrometric analysis, and it is often done at a micro-scale. In REU summer projects, students will work on different sample manipulations of peptides such as chemical modification of peptide mixtures and use mass spectrometry to study the efficiency of various micro-scale procedures for peptide sample preparation. The REU project will specifically investigate analytical challenges in mass spectrometric analysis of phosphopeptides. Phosphopeptides are fragments of phosphoproteins that are important regulators for cellular signaling. Analysis of protein phosphorylation is important to understand and treat various human diseases and to manipulate the fate of stem cells for therapeutic and regenerative applications. The REU researcher will study ß-elimination and Michael addition reactions of phosphopeptides. Objectives of the project are to minimize side reactions and maximize the efficiency of the sample preparation workflow that will be examined by high performance liquid chromatography and tandem mass spectrometry. Yao Group Web Site

Synthesis and application of metal and semiconductor nanoparticles Dr. Jing Zhao (Analytical and Physical Chemistry)

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ACS Publications

Accounts of Chemical Research welcomes proposals for the upcoming Special Issue: “Electrosynthesis of Inorganic Materials”

May 5, 2018

Electrosynthesis of inorganic substances has been instrumental in the growth and evolution of modern society. Electrodeposition is inarguably now the dominant synthetic strategy for critically important metals like aluminum and device components such as copper interconnects.

This Special Issue will explore new strategies and concepts in the electrochemical synthesis of inorganic materials.

To be considered for inclusion in this exciting Special Issue, please prepare a proposal of your full manuscript. A proposal is a one- or two-page document which includes a short description of the focused topic and a list of references to your work that would form the foundation of the final manuscript. Proposals must be submitted by Wednesday, June 15, 2022.

Full information about Accounts of Chemical Research Proposals and how to submit is available here .

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View all journals

Inorganic chemistry articles from across Nature Portfolio

Inorganic chemistry is the study of the structure, properties and reactions of all chemical elements and compounds except for organic compounds (hydrocarbons and their derivatives).

Lifting iron higher and higher

Biological and synthetic catalysts often utilize iron in high oxidation states (+IV and greater) to perform challenging molecular transformations. A coordination complex featuring an Fe(VII) ion has now been synthesized through sequential oxidations of nonheme iron–nitrido precursors.

Adam T. Fiedler
Laxmi Devkota

Related Subjects

Bioinorganic chemistry
Chemical bonding
Crystal field theory
Group theory
Organometallic chemistry
Solid-state chemistry

Latest Research and Reviews

Two-dimensional lead halide perovskite lateral homojunctions enabled by phase pinning

Hong et al. report 2D perovskite lateral homojunction consists of ordered and disordered phases, achieved by organic cation doping induced phase pinning, built upon which they develop tuneable optical properties under external stimuli and directional exciton diffusion in the homojunctions.

Huilong Hong
Songhao Guo
Yongping Fu

Carbon dioxide capture and functionalization by bis( N -heterocyclic carbene)-borylene complexes

Bis( N -heterocyclic carbene)-borylene complexes are capable of capturing and functionalizing CO 2 , but stable single-site-boron-carbon dioxide adducts are rarely reported. Here, the authors report the synthesis of a stable borylene-CO 2 complex as well as the functionalization of the captured CO 2 .

An-Ping Koh
Cheuk-Wai So

Upcycling of polyethylene to gasoline through a self-supplied hydrogen strategy in a layered self-pillared zeolite

The development of new methodologies to convert plastics into fuels without relying on noble metal-based catalysts is desirable. Now it is shown that a layered self-pillared zeolite enables the conversion of polyethylene to gasoline with a selectivity of 99% and yields of >80% without the need to use external hydrogen.

Optically induced charge-transfer in donor-acceptor-substituted p - and m - C 2 B 10 H 12 carboranes

Icosahedral carboranes have long been considered to be aromatic but the extent of conjugation between these clusters and their substituents is still being debated. Here the authors demonstrate carboranes as conjugated bridges in optical functional chromophores.

Marco Holzapfel

Slow magnetic relaxation in a europium(II) complex

This study introduces a Eu(II) single molecule magnet that exhibits slow magnetic relaxation at low temperatures. These results highlight the importance of the lanthanide ion’s crystal field in unlocking the magnet-like properties of Eu(II).

Dylan Errulat
Katie L. M. Harriman
Muralee Murugesu

Aggregation induced emission dynamic chiral europium(III) complexes with excellent circularly polarized luminescence and smart sensors

Chiral luminescent materials are of increasing interest in various applications, but achieving a desirable balance of properties can be challenging. Here, the authors report the development of Eu-based complexes with chiral luminescence and aggregation induced emission.

Hai-Ling Wang
Hua-Hong Zou

News and Comment

Like will reduce like

The reduction of molecular species containing arene to alkali metal cation interactions with other alkali metals has been found to contradict the expectation provided by simple considerations of relative reduction potentials.

Johannes Kreutzer

Doing away with radium’s proxies

Despite the growing clinical use of radium in cancer treatments, the fundamental chemistry of nature’s largest +2 cation remains largely unexplored. Now, structural analysis of a radium complex reveals that its behaviour cannot always be predicted from the chemistry of its closest nonradioactive congener, barium.

Joshua J. Woods
Rebecca J. Abergel

Achieving unusual metal–metal bonding in the s -block

Since the isolation of a Mg–Mg complex, research on low-oxidation-state s -block chemistry has flourished. An approach to forming metal–metal bonds between Mg and the heavier alkaline earth metals (Ca, Sr and Ba) is now demonstrated. The unusual electronic nature of these compounds could stimulate further discussions of metal–metal bonding.

Isotropic models for anisotropic inorganics

The study of disordered materials poses numerous challenges, and computational approaches have proved useful to supplement and support structural experiments. Now, an abstract computational model has been used to study the structure of amorphous calcium carbonate, providing mechanistic insights into the emergence of the disordered phase as well as its atomic-level configurations.

Julia Dshemuchadse

A 21-electron cobalt sandwich

Joan Serrano-Plana

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Original Research Proposal – Organic

General layout for 4th year orp.

Overview . The goal of the ORP is to have students come up with an independent research proposal. Your ORP should focus on a big picture problem in chemistry. You should pull from multiple areas outside of your area of expertise (synthesis, catalysis, electrochemistry, photochemistry, chemical biology, polymer/materials) to address a contemporary and unsolved problem . Each specific aim should be independent on each other (this will be one of the metrics we will use to assess the ORP). The scope of the project should be that of a postdoctoral fellowship – something that can be accomplished in 2-3 years by one postdoc.

Specific Aims PreORP . You must first submit a one-page, single spaced description of the Specific Aims of your proposal (see formatting requirements below). Consider it an executive summary of your planned proposal. It should include significance (how it fits into the broader field and how it advances the field), innovation, and summary of research plan broken up into 2-3 specific aims. The aims should all focus on solving the problem you laid out, but should be independent of each other (e.g. if Aim 1 fails, Aim 2 is still feasible). This must be approved before writing the full proposal.

An excellent guide for writing specific aims can be found here .

ORP. Once your Specific Aims are approved, you must submit a max 12 page double spaced proposal (see formatting requirements below). It should contain the following sections: Significance, Innovation, and Research Plan. The research plan should be broken up into each of your specific aims, and should describe how you will accomplish them. At the end of each specific aim, you should describe potential problems and how you will address them. Include a concluding paragraph indicating what will be accomplished if the proposal is successful.

Formatting requirements : Times New Roman, Arial, or Helvetica. Font size 11 pt. Margins 1 in. Font color: black. Total length of document: Maximum 1 page single spaced for Specific Aims PreORP; 15 pages max double spaced for ORP. Alignment – Justify (i.e. straight edges like in journal articles). Figures should help to communicate the ideas in the proposal. Use ACS 1996 Template in Chemdraw.

Saving Files

For the ORP document: Last Name_ORP Year For the ORP Prep Proposal: Last Name_PreORP Year For the ORP Resubmission: Last Name_ORP Year_Resubmit#

Example: WilkersonHill_ORP2020 for the first draft and WilkersonHill_ORP2020_Resubmit2 for the resubmit

4th year ORP Grading Rubric

Each proposal is reviewed by two faculty members who are not the student’s advisor. Anonymized feedback is returned to students within two months of submission. Proposals are graded Pass or Fail. A failed proposal may be revised and resubmitted up to one month after student notification.

Student name:

Proposal title:

Overall Impact

Reviewers will provide an overall impact score to reflect their assessment of the likelihood for the project to exert a sustained, powerful influence on the research field(s) involved, in consideration of the following three scored review criteria.

Scored Review Criteria

Reviewers will consider each of the three review criteria below in the determination of scientific and technical merit, and give a separate score for each.

Final Ranking

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Home » 300+ Chemistry Research Topics

300+ Chemistry Research Topics

Table of Contents

Chemistry is a fascinating and complex field that explores the composition, properties, and behavior of matter at the molecular and atomic level. As a result, there are numerous chemistry research topics that can be explored, ranging from the development of new materials and drugs to the study of natural compounds and the environment. In this rapidly evolving field, researchers are constantly uncovering new insights and pushing the boundaries of our understanding of chemistry. Whether you are a student, a professional researcher, or simply curious about the world around you, there is always something new to discover in the field of chemistry. In this post, we will explore some of the exciting and important research topics in chemistry today.

Chemistry Research Topics

Chemistry Research Topics are as follows:

Organic Chemistry Research Topics

Organic Chemistry Research Topics are as follows:

Development of novel synthetic routes for the production of biologically active natural products
Investigation of reaction mechanisms and kinetics for organic transformations
Design and synthesis of new catalysts for asymmetric organic reactions
Synthesis and characterization of chiral compounds for pharmaceutical applications
Development of sustainable methods for the synthesis of organic molecules using renewable resources
Discovery of new reaction pathways for the conversion of biomass into high-value chemicals
Study of molecular recognition and host-guest interactions for drug design
Design and synthesis of new materials for energy storage and conversion
Development of efficient and selective methods for C-H functionalization reactions
Exploration of the reactivity of reactive intermediates such as radicals and carbenes
Study of supramolecular chemistry and self-assembly of organic molecules
Development of new methods for the synthesis of heterocyclic compounds
Investigation of the biological activities and mechanisms of action of natural products
Synthesis of polymeric materials with controlled architecture and functionality
Development of new synthetic methodologies for the preparation of bioconjugates
Investigation of the mechanisms of enzyme catalysis and the design of enzyme inhibitors
Synthesis and characterization of novel fluorescent probes for biological imaging
Development of new synthetic strategies for the preparation of carbohydrates and glycoconjugates
Study of the properties and reactivity of carbon nanomaterials
Design and synthesis of novel drugs for the treatment of diseases such as cancer, diabetes, and Alzheimer’s disease.

Inorganic Chemistry Research Topics

Inorganic Chemistry Research Topics are as follows:

Synthesis and characterization of new metal-organic frameworks (MOFs) for gas storage and separation applications
Development of new catalysts for sustainable chemical synthesis reactions
Investigation of the electronic and magnetic properties of transition metal complexes for spintronics applications
Synthesis and characterization of novel nanomaterials for energy storage applications
Development of new ligands for metal coordination complexes with potential medical applications
Investigation of the mechanism of metal-catalyzed reactions using advanced spectroscopic techniques
Synthesis and characterization of new inorganic materials for photocatalytic water splitting
Development of new materials for electrochemical carbon dioxide reduction reactions
Investigation of the properties of transition metal oxides for energy storage and conversion applications
Synthesis and characterization of new metal chalcogenides for optoelectronic applications
Development of new methods for the preparation of inorganic nanoparticles with controlled size and shape
Investigation of the reactivity and catalytic properties of metal clusters
Synthesis and characterization of new metal-organic polyhedra (MOPs) for gas storage and separation applications
Development of new methods for the synthesis of metal nanoparticles using environmentally friendly reducing agents
Investigation of the properties of metal-organic frameworks for gas sensing applications
Synthesis and characterization of new coordination polymers with potential magnetic and electronic properties
Development of new materials for electrocatalytic water oxidation reactions
Investigation of the properties of metal-organic frameworks for carbon capture and storage applications
Synthesis and characterization of new metal-containing polymers with potential applications in electronics and energy storage
Development of new methods for the synthesis of metal-organic frameworks using green solvents and renewable resources.

Physical Chemistry Research Topics

Physical Chemistry Research Topics are as follows:

Investigation of the properties and interactions of ionic liquids in aqueous and non-aqueous solutions.
Development of advanced analytical techniques for the study of protein structure and dynamics.
Investigation of the thermodynamic properties of supercritical fluids for use in industrial applications.
Development of novel nanomaterials for energy storage applications.
Studies of the surface chemistry of catalysts for the optimization of their performance in chemical reactions.
Development of new methods for the synthesis of complex organic molecules with improved yields and selectivity.
Investigation of the molecular mechanisms involved in the catalysis of biochemical reactions.
Development of new strategies for the controlled release of drugs and other bioactive molecules.
Studies of the interaction of nanoparticles with biological systems for biomedical applications.
Investigation of the thermodynamic properties of materials under extreme conditions of temperature and pressure.
Development of new methods for the characterization of materials at the nanoscale.
Investigation of the electronic and magnetic properties of materials for use in spintronics.
Development of new materials for energy conversion and storage.
Studies of the kinetics and thermodynamics of adsorption processes on surfaces.
Investigation of the transport properties of ionic liquids for use in energy storage and conversion devices.
Development of new materials for the capture and sequestration of greenhouse gases.
Studies of the structure and properties of biomolecules for use in drug design and development.
Investigation of the dynamics of chemical reactions in solution using time-resolved spectroscopic techniques.
Development of new approaches for the synthesis of metallic and semiconductor nanoparticles with controlled size and shape.
Studies of the structure and properties of materials for use in electrochemical energy storage devices.

Analytical Chemistry Research Topics

Analytical Chemistry Research Topics are as follows:

Development and optimization of analytical techniques for the quantification of trace elements in food and environmental samples.
Design and synthesis of novel analytical probes for the detection of biomolecules in complex matrices.
Investigation of the fundamental mechanisms involved in the separation and detection of complex mixtures using chromatographic techniques.
Development of sensors and biosensors for the detection of chemical and biological species in real-time.
Investigation of the chemical and structural properties of nanomaterials and their applications in analytical chemistry.
Development and validation of analytical methods for the quantification of contaminants and pollutants in water, air, and soil.
Investigation of the molecular mechanisms underlying drug metabolism and toxicity using mass spectrometry.
Development of analytical tools for the identification and quantification of drugs of abuse in biological matrices.
Investigation of the chemical composition and properties of natural products and their applications in medicine and food science.
Development of advanced analytical techniques for the characterization of proteins and peptides.
Investigation of the chemistry and mechanism of action of antioxidants in foods and their impact on human health.
Development of analytical methods for the detection and quantification of microorganisms in food and environmental samples.
Investigation of the molecular mechanisms involved in the biosynthesis and degradation of important biomolecules such as proteins, carbohydrates, and lipids.
Development of analytical methods for the detection and quantification of environmental toxins and their impact on human health.
Investigation of the structure and properties of biological membranes and their role in drug delivery and disease.
Development of analytical techniques for the characterization of complex mixtures such as petroleum and crude oil.
Investigation of the chemistry and mechanism of action of natural and synthetic dyes.
Development of analytical techniques for the detection and quantification of pharmaceuticals and personal care products in water and wastewater.
Investigation of the chemical composition and properties of biopolymers and their applications in biomedicine and biomaterials.
Development of analytical methods for the identification and quantification of essential nutrients and vitamins in food and dietary supplements.

Biochemistry Research Topics

Biochemistry Research Topics are as follows:

The role of enzymes in metabolic pathways
The biochemistry of DNA replication and repair
Protein folding and misfolding diseases
Lipid metabolism and the pathogenesis of atherosclerosis
The role of vitamins and minerals in human metabolism
Biochemistry of cancer and the development of targeted therapies
The biochemistry of signal transduction pathways and their regulation
The mechanisms of antibiotic resistance in bacteria
The biochemistry of neurotransmitters and their roles in behavior and disease
The role of oxidative stress in aging and age-related diseases
The biochemistry of microbial fermentation and its applications in industry
The biochemistry of the immune system and its response to pathogens
The biochemistry of plant metabolism and its regulation
The molecular basis of genetic diseases and gene therapy
The biochemistry of membrane transport and its role in cell function
The biochemistry of muscle contraction and its regulation
The role of lipids in membrane structure and function
The biochemistry of photosynthesis and its regulation
The biochemistry of RNA splicing and alternative splicing events
The biochemistry of epigenetics and its regulation in gene expression.

Environmental Chemistry Research Topics

Environmental Chemistry Research Topics are as follows:

Investigating the effects of microplastics on aquatic ecosystems and their potential impact on human health.
Examining the impact of climate change on soil quality and nutrient availability in agricultural systems.
Developing methods to improve the removal of heavy metals from contaminated soils and waterways.
Assessing the effectiveness of natural and synthetic antioxidants in mitigating the effects of air pollution on human health.
Investigating the potential for using algae and other microorganisms to sequester carbon dioxide from the atmosphere.
Studying the role of biodegradable plastics in reducing plastic waste and their impact on the environment.
Examining the impact of pesticides and other agricultural chemicals on water quality and the health of aquatic organisms.
Investigating the effects of ocean acidification on marine organisms and ecosystems.
Developing new materials and technologies to reduce carbon emissions from industrial processes.
Evaluating the effectiveness of phytoremediation in cleaning up contaminated soils and waterways.
Studying the impact of microplastics on terrestrial ecosystems and their potential to enter the food chain.
Developing sustainable methods for managing and recycling electronic waste.
Investigating the role of natural processes, such as weathering and erosion, in regulating atmospheric carbon dioxide levels.
Assessing the impact of urbanization on air quality and developing strategies to mitigate pollution in cities.
Examining the effects of climate change on the distribution and abundance of species in different ecosystems.
Investigating the impact of ocean currents on the distribution of pollutants and other environmental contaminants.
Developing new materials and technologies for renewable energy generation and storage.
Studying the effects of deforestation on soil quality, water availability, and biodiversity.
Assessing the potential for using waste materials, such as agricultural residues and municipal solid waste, as sources of renewable energy.
Investigating the role of natural and synthetic chemicals in regulating ecosystem functions, such as nutrient cycling and carbon sequestration.

Polymer Chemistry Research Topics

Polymer Chemistry Research Topics are as follows:

Development of new monomers for high-performance polymers
Synthesis and characterization of biodegradable polymers for sustainable packaging
Design of stimuli-responsive polymers for drug delivery applications
Investigation of the properties and applications of conductive polymers
Development of new catalysts for controlled/living polymerization
Synthesis of polymers with tailored mechanical properties
Characterization of the structure-property relationship in polymer nanocomposites
Study of the impact of polymer architecture on material properties
Design and synthesis of new polymeric materials for energy storage
Development of high-throughput methods for polymer synthesis and characterization
Exploration of new strategies for polymer recycling and upcycling
Synthesis and characterization of responsive polymer networks for smart textiles
Design of advanced polymer coatings with self-healing properties
Investigation of the impact of processing conditions on the morphology and properties of polymer materials
Study of the interactions between polymers and biological systems
Development of biocompatible polymers for tissue engineering applications
Synthesis and characterization of block copolymers for advanced membrane applications
Exploration of the potential of polymer-based sensors and actuators
Design of novel polymer electrolytes for advanced batteries and fuel cells
Study of the behavior of polymers under extreme conditions, such as high pressure or temperature.

Materials Chemistry Research Topics

Materials Chemistry Research Topics are as follows:

Development of new advanced materials for energy storage and conversion
Synthesis and characterization of nanomaterials for environmental remediation
Design and fabrication of stimuli-responsive materials for drug delivery
Investigation of electrocatalytic materials for fuel cells and electrolysis
Fabrication of flexible and stretchable electronic materials for wearable devices
Development of novel materials for high-performance electronic devices
Exploration of organic-inorganic hybrid materials for optoelectronic applications
Study of corrosion-resistant coatings for metallic materials
Investigation of biomaterials for tissue engineering and regenerative medicine
Synthesis and characterization of metal-organic frameworks for gas storage and separation
Design and fabrication of new materials for water purification
Investigation of carbon-based materials for supercapacitors and batteries
Synthesis and characterization of self-healing materials for structural applications
Development of new materials for catalysis and chemical reactions
Exploration of magnetic materials for spintronic devices
Investigation of thermoelectric materials for energy conversion
Study of 2D materials for electronic and optoelectronic applications
Development of sustainable and eco-friendly materials for packaging
Fabrication of advanced materials for sensors and actuators
Investigation of materials for high-temperature applications such as aerospace and nuclear industries.

Nuclear Chemistry Research Topics

Nuclear Chemistry Research Topics are as follows:

Nuclear fission and fusion reactions
Nuclear power plant safety and radiation protection
Radioactive waste management and disposal
Nuclear fuel cycle and waste reprocessing
Nuclear energy and its impact on climate change
Radiation therapy for cancer treatment
Radiopharmaceuticals for medical imaging
Nuclear medicine and its role in diagnostics
Nuclear forensics and nuclear security
Isotopic analysis in environmental monitoring and pollution control
Nuclear magnetic resonance (NMR) spectroscopy
Nuclear magnetic resonance imaging (MRI)
Radiation damage in materials and radiation effects on electronic devices
Nuclear data evaluation and validation
Nuclear reactors design and optimization
Nuclear fuel performance and irradiation behavior
Nuclear energy systems integration and optimization
Neutron and gamma-ray detection and measurement techniques
Nuclear astrophysics and cosmology
Nuclear weapons proliferation and disarmament.

Medicinal Chemistry Research Topics

Medicinal Chemistry Research Topics are as follows:

Drug discovery and development
Design and synthesis of novel drugs
Medicinal chemistry of natural products
Structure-activity relationships (SAR) of drugs
Rational drug design using computational methods
Target identification and validation
Drug metabolism and pharmacokinetics (DMPK)
Drug delivery systems
Development of new antibiotics
Design of drugs for the treatment of cancer
Development of drugs for the treatment of neurological disorders
Medicinal chemistry of peptides and proteins
Development of drugs for the treatment of infectious diseases
Discovery of new antiviral agents
Design of drugs for the treatment of cardiovascular diseases
Medicinal chemistry of enzyme inhibitors
Development of drugs for the treatment of inflammatory diseases
Design of drugs for the treatment of metabolic disorders
Medicinal chemistry of anti-cancer agents
Development of drugs for the treatment of rare diseases.

Food Chemistry Research Topics

Food Chemistry Research Topics are as follows:

Investigating the effect of cooking methods on the nutritional value of food.
Analyzing the role of antioxidants in preventing food spoilage and degradation.
Examining the effect of food processing techniques on the nutritional value of fruits and vegetables.
Studying the chemistry of food additives and their impact on human health.
Evaluating the role of enzymes in food digestion and processing.
Investigating the chemical properties and functional uses of food proteins.
Analyzing the effect of food packaging materials on the quality and safety of food products.
Examining the chemistry of food flavorings and the impact of flavor on consumer acceptance.
Studying the role of carbohydrates in food texture and structure.
Investigating the chemistry of food lipids and their impact on human health.
Analyzing the chemical properties and functional uses of food gums and emulsifiers.
Examining the effect of processing on the flavor and aroma of food products.
Studying the chemistry of food preservatives and their impact on food safety.
Investigating the chemical properties and functional uses of food fibers.
Analyzing the effect of food processing on the bioavailability of nutrients.
Examining the chemistry of food colorants and their impact on consumer acceptance.
Studying the role of vitamins and minerals in food and their impact on human health.
Investigating the chemical properties and functional uses of food hydrocolloids.
Analyzing the effect of food processing on the allergenicity of food products.
Examining the chemistry of food sweeteners and their impact on human health.

Industrial Chemistry Research Topics

Industrial Chemistry Research Topics are as follows:

Development of catalysts for selective hydrogenation reactions in the petrochemical industry.
Green chemistry approaches for the synthesis of biodegradable polymers from renewable sources.
Optimization of solvent extraction processes for the separation of rare earth elements from ores.
Development of novel materials for energy storage applications, such as lithium-ion batteries.
Production of biofuels from non-food sources, such as algae or waste biomass.
Application of computational chemistry to optimize the design of new catalysts and materials.
Design and optimization of continuous flow processes for large-scale chemical production.
Development of new synthetic routes for the production of pharmaceutical intermediates.
Investigation of the environmental impact of industrial processes and development of sustainable alternatives.
Development of innovative water treatment technologies for industrial wastewater.
Synthesis of functionalized nanoparticles for use in drug delivery and other biomedical applications.
Optimization of processes for the production of high-performance polymers, such as polyamides or polyesters.
Design and optimization of process control strategies for efficient and safe chemical production.
Development of new methods for the detection and removal of heavy metal ions from industrial effluents.
Investigation of the behavior of surfactants in complex mixtures, such as crude oil or food products.
Development of new materials for catalytic oxidation reactions, such as the removal of volatile organic compounds from air.
Investigation of the properties and behavior of materials under extreme conditions, such as high pressure or high temperature.
Development of new processes for the production of chemicals from renewable resources, such as bio-based building blocks.
Study of the kinetics and mechanism of chemical reactions in complex systems, such as multi-phase reactors.
Optimization of the production of fine chemicals, such as flavors and fragrances, using biocatalytic processes.

Computational Chemistry Research Topics

Computational Chemistry Research Topics are as follows:

Development and application of machine learning algorithms for predicting chemical reactions and properties.
Investigation of the role of solvents in chemical reactions using molecular dynamics simulations.
Modeling and simulation of protein-ligand interactions to aid drug design.
Study of the electronic structure and reactivity of catalysts for sustainable energy production.
Analysis of the thermodynamics and kinetics of complex chemical reactions using quantum chemistry methods.
Exploration of the mechanism and kinetics of enzyme-catalyzed reactions using molecular dynamics simulations.
Investigation of the properties and behavior of nanoparticles using computational modeling.
Development of computational tools for the prediction of chemical toxicity and environmental impact.
Study of the electronic properties of graphene and other 2D materials for applications in electronics and energy storage.
Investigation of the mechanisms of protein folding and aggregation using molecular dynamics simulations.
Development and optimization of computational methods for calculating thermodynamic properties of liquids and solids.
Study of the properties of supercritical fluids for applications in separation and extraction processes.
Development of new methods for the calculation of electron transfer rates in complex systems.
Investigation of the electronic and mechanical properties of carbon nanotubes for applications in nanoelectronics and nanocomposites.
Development of new approaches for modeling the interaction of biomolecules with biological membranes.
Study of the mechanisms of charge transfer in molecular and hybrid solar cells.
Analysis of the structural and mechanical properties of materials under extreme conditions using molecular dynamics simulations.
Development of new approaches for the calculation of free energy differences in complex systems.
Investigation of the reaction mechanisms of metalloenzymes using quantum mechanics/molecular mechanics (QM/MM) methods.
Study of the properties of ionic liquids for applications in catalysis and energy storage.

Theoretical Chemistry Research Topics

Theoretical Chemistry Research Topics are as follows:

Quantum Chemical Studies of Excited State Processes in Organic Molecules
Theoretical Investigation of Structure and Reactivity of Metal-Organic Frameworks
Computational Modeling of Reaction Mechanisms and Kinetics in Enzyme Catalysis
Theoretical Investigation of Non-Covalent Interactions in Supramolecular Chemistry
Quantum Chemical Studies of Photochemical Processes in Organic Molecules
Theoretical Analysis of Charge Transport in Organic and Inorganic Materials
Computational Modeling of Protein Folding and Dynamics
Quantum Chemical Investigations of Electron Transfer Processes in Complex Systems
Theoretical Studies of Surface Chemistry and Catalysis
Computational Design of Novel Materials for Energy Storage Applications
Theoretical Analysis of Chemical Bonding and Molecular Orbital Theory
Quantum Chemical Investigations of Magnetic Properties of Complex Systems
Computational Modeling of Biological Membranes and Transport Processes
Theoretical Studies of Nonlinear Optical Properties of Molecules and Materials
Quantum Chemical Studies of Spectroscopic Properties of Molecules
Theoretical Investigations of Reaction Mechanisms in Organometallic Chemistry
Computational Modeling of Heterogeneous Catalysis
Quantum Chemical Studies of Excited State Dynamics in Photosynthesis
Theoretical Analysis of Chemical Reaction Networks
Computational Design of Nanomaterials for Biomedical Applications

Astrochemistry Research Topics

Astrochemistry Research Topics are as follows:

Investigating the chemical composition of protoplanetary disks and its implications for planet formation
Examining the role of magnetic fields in the formation of complex organic molecules in space
Studying the effects of interstellar radiation on the chemical evolution of molecular clouds
Exploring the chemistry of comets and asteroids to better understand the early solar system
Investigating the origin and evolution of interstellar dust and its relationship to organic molecules
Examining the formation and destruction of interstellar molecules in shocked gas
Studying the chemical processes that occur in the atmospheres of planets and moons in our solar system
Exploring the possibility of life on other planets through astrobiology and astrochemistry
Investigating the chemistry of planetary nebulae and their role in the evolution of stars
Studying the chemical properties of exoplanets and their potential habitability
Examining the chemical reactions that occur in the interstellar medium
Investigating the chemical composition of supernova remnants and their impact on the evolution of galaxies
Studying the chemical composition of interstellar grains and their role in the formation of stars and planets
Exploring the chemistry of astrocytes and their role in the evolution of galaxies
Investigating the formation of interstellar ice and its implications for the origin of life
Examining the chemistry of molecular clouds and its relationship to star formation
Studying the chemical composition of the interstellar medium in different galaxies and how it varies
Investigating the role of cosmic rays in the formation of complex organic molecules in space
Exploring the chemical properties of interstellar filaments and their relationship to star formation
Studying the chemistry of protostars and the role of turbulence in the formation of stars.

Geochemistry Research Topics

Geochemistry Research Topics are as follows:

Understanding the role of mineralogical and geochemical factors on metal mobility in contaminated soils
Investigating the sources and fate of dissolved organic matter in aquatic systems
Exploring the geochemical signatures of ancient sedimentary rocks to reconstruct Earth’s past atmospheric conditions
Studying the impacts of land-use change on soil organic matter content and quality
Investigating the impact of acid mine drainage on water quality and ecosystem health
Examining the processes controlling the behavior and fate of emerging contaminants in the environment
Characterizing the organic matter composition of shale gas formations to better understand hydrocarbon storage and migration
Evaluating the potential for carbon capture and storage in geologic formations
Investigating the geochemical processes controlling the formation and evolution of ore deposits
Studying the geochemistry of geothermal systems to better understand energy production potential and environmental impacts
Exploring the impacts of climate change on the biogeochemistry of terrestrial ecosystems
Investigating the geochemical cycling of nutrients in coastal marine environments
Characterizing the isotopic composition of minerals and fluids to understand Earth’s evolution
Developing new analytical techniques to better understand the chemistry of natural waters
Studying the impact of anthropogenic activities on the geochemistry of urban soils
Investigating the role of microbial processes in geochemical cycling of elements in soils and sediments
Examining the impact of wildfires on soil and water chemistry
Characterizing the geochemistry of mineral dust and its impact on climate and biogeochemical cycles
Investigating the geochemical factors controlling the release and transport of contaminants from mine tailings
Exploring the biogeochemistry of wetlands and their role in carbon sequestration and nutrient cycling.

Electrochemistry Research Topics

Electrochemistry Research Topics are as follows:

Development of high-performance electrocatalysts for efficient electrochemical conversion of CO2 to fuels and chemicals
Investigation of electrode-electrolyte interfaces in lithium-ion batteries for enhanced battery performance and durability
Design and synthesis of novel electrolytes for high-energy-density and stable lithium-sulfur batteries
Development of advanced electrochemical sensors for the detection of trace-levels of analytes in biological and environmental samples
Analysis of the electrochemical behavior of new materials and their electrocatalytic properties in fuel cells
Study of the kinetics of electrochemical reactions and their effect on the efficiency and selectivity of electrochemical processes
Development of novel strategies for the electrochemical synthesis of value-added chemicals from biomass and waste materials
Analysis of the electrochemical properties of metal-organic frameworks (MOFs) for energy storage and conversion applications
Investigation of the electrochemical degradation mechanisms of polymer electrolyte membranes in fuel cells
Study of the electrochemical properties of 2D materials and their applications in energy storage and conversion devices
Development of efficient electrochemical systems for desalination and water treatment applications
Investigation of the electrochemical properties of metal-oxide nanoparticles for energy storage and conversion applications
Analysis of the electrochemical behavior of redox-active organic molecules and their application in energy storage and conversion devices
Study of the electrochemical behavior of metal-organic frameworks (MOFs) for the catalytic conversion of CO2 to value-added chemicals
Development of novel electrode materials for electrochemical capacitors with high energy density and fast charge/discharge rates
Investigation of the electrochemical properties of perovskite materials for energy storage and conversion applications
Study of the electrochemical behavior of enzymes and their application in bioelectrochemical systems
Development of advanced electrochemical techniques for the characterization of interfacial processes in electrochemical systems
Analysis of the electrochemical behavior of nanocarbons and their application in electrochemical energy storage devices
Investigation of the electrochemical properties of ionic liquids for energy storage and conversion applications.

Surface Chemistry Research Topics

Surface Chemistry Research Topics are as follows:

Surface modification of nanoparticles for enhanced catalytic activity
Investigating the effect of surface roughness on the wetting behavior of materials
Development of new materials for solar cell applications through surface chemistry techniques
Surface chemistry of graphene and its applications in electronic devices
Surface functionalization of biomaterials for biomedical applications
Characterization of surface defects and their effect on material properties
Surface modification of carbon nanotubes for energy storage applications
Developing surface coatings for corrosion protection of metals
Synthesis of self-assembled monolayers on surfaces for sensor applications
Surface chemistry of metal-organic frameworks for gas storage and separation
Investigating the role of surface charge in protein adsorption
Developing surfaces with superhydrophobic or superoleophobic properties for self-cleaning applications
Surface functionalization of nanoparticles for drug delivery applications
Surface chemistry of semiconductors and its effect on photovoltaic properties
Development of surface-enhanced Raman scattering (SERS) substrates for trace analyte detection
Surface functionalization of graphene oxide for water purification applications
Investigating the role of surface tension in emulsion formation and stabilization
Surface modification of membranes for water desalination and purification
Synthesis and characterization of metal nanoparticles for catalytic applications
Development of surfaces with controlled wettability for microfluidic applications.

Atmospheric Chemistry Research Topics

Atmospheric Chemistry Research Topics are as follows:

The impact of wildfires on atmospheric chemistry
The role of aerosols in atmospheric chemistry
The chemistry and physics of ozone depletion in the stratosphere
The chemistry and dynamics of the upper atmosphere
The impact of anthropogenic emissions on atmospheric chemistry
The role of clouds in atmospheric chemistry
The chemistry of atmospheric particulate matter
The impact of nitrogen oxides on atmospheric chemistry and air quality
The effects of climate change on atmospheric chemistry
The impact of atmospheric chemistry on climate change
The chemistry and physics of atmospheric mercury cycling
The impact of volcanic eruptions on atmospheric chemistry
The chemistry and physics of acid rain formation and effects
The role of halogen chemistry in the atmosphere
The chemistry of atmospheric radicals and their impact on air quality and health
The impact of urbanization on atmospheric chemistry
The chemistry and physics of stratospheric polar vortex dynamics
The role of natural sources (e.g. ocean, plants) in atmospheric chemistry
The impact of atmospheric chemistry on the biosphere
The chemistry and dynamics of the ozone hole over Antarctica.

Photochemistry Research Topics

Photochemistry Research Topics are as follows:

Investigating the mechanisms of photoinduced electron transfer reactions in organic photovoltaic materials.
Developing novel photoredox catalysts for photochemical reactions.
Understanding the effects of light on DNA and RNA stability and replication.
Studying the photochemistry of atmospheric pollutants and their impact on air quality.
Designing new photoresponsive materials for advanced photonic and electronic devices.
Exploring the photochemistry of metalloporphyrins for potential applications in catalysis.
Investigating the photochemistry of transition metal complexes and their use as photodynamic therapy agents.
Developing new photocatalytic systems for sustainable energy production.
Studying the photochemistry of natural products and their potential pharmaceutical applications.
Investigating the role of light in the formation and degradation of environmental contaminants.
Designing new photochromic materials for smart windows and displays.
Exploring the photochemistry of carbon nanomaterials for energy storage and conversion.
Developing new light-driven molecular machines for nanotechnology applications.
Investigating the photochemistry of organic dyes for potential applications in dye-sensitized solar cells.
Studying the effects of light on the behavior of biological macromolecules.
Designing new photoresponsive hydrogels for drug delivery applications.
Exploring the photochemistry of semiconductor nanoparticles for potential applications in quantum computing.
Investigating the mechanisms of photochemical reactions in ionic liquids.
Developing new photonic sensors for chemical and biological detection.
Studying the photochemistry of transition metal complexes for potential applications in water splitting and hydrogen production.

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PDF Writing the research proposal: Chemistry 419/519
"A problem exists of social and research importance (territory). Some research already exists, but there is also clearly an absence of research in a particular area (gap). The researcher(s) is/are well prepared (means) to address the problem (goal) by conducting the following study (methodology)."
Original Research Proposal
Guidelines for Proposal Abstract. Students will submit a two-page abstract that the faculty will evaluate for feasibility as a topic for a full proposal. The abstract should succinctly describe the gap in knowledge, outline the proposed research to fill the gap, and describe the impact of the proposed work. Graphical content is encouraged.
PDF Original Proposal Field Survival Manual
You are about to write an original proposal on a topic in chemistry. Find an area of research that you find interesting. Read about that area. Then propose some experiments to do that will forward the field of research- or create a new field of research. The area of your proposal can be anything within the broad definition of chemistry. Your ...
PDF research proposal final
Friday, November 7, 2003. 10:00 AM, Room 154. 1. Introduction. Metal nanoparticles are of great interest in many areas because of their unique physical and chemical properties. For example, if the size of particles is reduced to the nanometer scale, their electronic and optical properties change depending on their size.
PDF Writing Excellent Research Proposals
General Outline for Research Grant Proposals. Abstract - often written in slightly more general terms, readable by non-experts. Background and Significance - demonstrate that you know the field thoroughly. Specific Aims - 1-2 sentences on each point that you intend to investigate. Experimental Plan.
(PDF) Research Proposal Activities in an Advanced Inorganic Chemistry
Didáctica de la Quìmica "Research Proposal Activities in an Advanced Inorganic Chemistry Lecture at the Undergraduate Level", Peter J. Rosado Flores Vol. 29 | Núm. 4 | Págs. 28 - 35 | Octubre 2018 DOI: 10.22201/fq.18708404e.2018.4.64766 RESEARCH PROPOSAL ACTIVITIES IN AN ADVANCED INORGANIC CHEMISTRY LECTURE AT THE UNDERGRADUATE LEVEL Abstract With cutting edge research comes the ...
35911 Overview of the Research Proposal
In this module, we focus on writing a research proposal, a document written to request financial support for an ongoing or newly conceived research project. Like the journal article (module 1), the proposal is one of the most important and most utilized writing genres in chemistry. Chemists employed in a wide range of disciplines including ...
PDF Department of Chemistry Research Proposal Rubric
Proposal Format The research proposal is well organized and is of appropriate length. The background, significance of the work, related preliminary results (or examples from the literature), broader impacts of the work and a concise summary are all included in the proposal. References are appropriately formatted. The research proposal is well ...
PDF Research proposal
5.Abstract. The project aims fundamental research on the photovoltaic applications of self assembled organic nanofibers. The ability of small organic molecules to form nanostructures will be investigated in order to enhance the efficiency of photovoltaic cells. The morphology of the polymer-nanostructures blends will be analyzed by means of X ...
University of Wisconsin-Madison
An original research proposal is required of Ph. D. candidates in organic chemistry. Recognition and development of original and meaningful research problems is an important aspect of the work of a Ph.D. scientist. This requirement is intended to help you develop your skills in selecting a research problem and writing a research proposal.
Research Projects
Research projects: complete list. Surface interaction and dynamics of molecular spin-probes as guests in tailor-made organosilica, porous hosts for applications in chromatography. Mass transport in, trough and out of porous solids is a deciding factor in a number of applications in process engineering, e.g. chromatography.
PDF MOAC PhD-project proposal
the interface between inorganic chemistry, biology, and medicine for 30+ years. ... Research Proposal A. Aims i. To develop a biotin-linked-photoactivatable cisplatin analog which, when bound to proteins, can be ... Determination of PTM's in proteins requires the sample be reasonably clean and that the reaction is reasonably homogeneous. In ...
Proposal
The Topic. 1. Ideally, the proposal should take advantage of fundamental principles from a graduate course (s) you are taking this quarter: e.g., Chem 201 Organic Reaction Mechanisms, Chem 215 Inorganic Chemistry, Chem 216 Organometallic Chemistry, Chem 223 Biomacromolecules. 2.
PDF Uide to The Graduate Program Requirements for The Ph.d. in Inorganic
D) Original research proposal The primary goal of the Ph.D. degree program is for you to conduct original research in inorganic chemistry. To develop your ability to design an original research project, you will prepare a research proposal on a topic unrelated to your thesis research. You will present a
Inorganic Chemistry
Inorganic Chemistry. Inorganic chemistry is concerned with the properties and behavior of inorganic metals, minerals, and organometallic compounds. The critical distinction from organic chemistry is that inorganic compounds do not contain carbon. But there can be overlap; for example, organometallic compounds usually contain a metal or ...
Research Proposal Activities in an Advanced Inorganic Chemistry Lecture
Research Proposal Activities in an Advanced Inorganic Chemistry Lecture at the Undergraduate Level. Actividades de escritura de propuestas en una clase de Química Inorgánica avanzada a nivel pre-doctoral. Peter J. Rosado Flores * * Department of Chemistry, Physics & Astronomy Milledgeville, Georgia College and State University. USA. ...
Inorganic Chemistry
Modern inorganic chemistry is an exciting undertaking, embracing a range of rapidly evolving interdisciplinary fields. At the University of Iowa, inorganic research interests encompass many interdisciplinary topics including biological, environmental, radiochemistry, materials and catalysis, and organometallics.
Proposed Research Projects
We use synthetic chemistry, both organic and inorganic, as a tool to design and build new molecules for targeted applications. We are particularly interested in the social dilemmas of climate change and antibiotic resistance. Interestingly, both problems can be thought as examples of tragedies of the commons. Our current research efforts are ...
Accounts of Chemical Research welcomes proposals for the upcoming
A proposal is a one- or two-page document which includes a short description of the focused topic and a list of references to your work that would form the foundation of the final manuscript. Proposals must be submitted by Wednesday, June 15, 2022. Full information about Accounts of Chemical Research Proposals and how to submit is available here.
Inorganic chemistry
Inorganic chemistry is the study of the structure, properties and reactions of all chemical elements and compounds except for organic compounds (hydrocarbons and their derivatives). Biological and ...
CURRENT RESEARCH TOPICS IN BIOINORGANIC CHEMISTRY
Work at the interface between the areas of inorganic and biological chem- istry has greatly intensified in recent years. Organization of the subject material of this growing field of bioinorganic chemistry along topical lines is fairly straightforward, if not completely satisfying. Thus whole litera- tures have grown up around such problems as nitrogen fixation, heme
Original Research Proposal
Overview. The goal of the ORP is to have students come up with an independent research proposal. Your ORP should focus on a big picture problem in chemistry. You should pull from multiple areas outside of your area of expertise (synthesis, catalysis, electrochemistry, photochemistry, chemical biology, polymer/materials) to address a ...
Inorganic Chemistry (research proposal form) PhD Research ...
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300+ Chemistry Research Topics
Organic Chemistry Research Topics. Organic Chemistry Research Topics are as follows: Development of novel synthetic routes for the production of biologically active natural products. Investigation of reaction mechanisms and kinetics for organic transformations. Design and synthesis of new catalysts for asymmetric organic reactions.

Research Proposal Activities in an Advanced Inorganic Chemistry Lecture at the Undergraduate Level

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Research Projects at the Institute of Inorganic Chemistry

Organic Reaction Mechanisms

Inorganic Chemistry

Inorganic chemistry faculty

Korey Carter

Scott R. Daly

Tori Z. Forbes

Edward G. Gillan

Lou Messerle

Chemistry REU Program

Polymer Based Vesicles for Therapeutics Dr. Douglas Adamson (Polymer Chemistry)

Mechanistic Inorganic Chemistry Dr. Alfredo Angeles-Boza (Inorganic Chemistry)

Use of Persistent Radical Catalysts in Living Polymerization Reactions Dr. Alexandru Asandei (Polymer Chemistry)

Synthesis and Study of DNA Damages Dr. Ashis K. Basu (Bioorganic Chemistry)

Synthesis of Pyrrole-Modified Porphyrins Dr. Christian Brueckner (Organic Chemistry)

Modeling the Mechanisms of Light Harvesting in a Photosynthetic Antenna Protein Dr. Jose Gascon (Physical and Computational Chemistry)

Automated Continuous Flow Chemistries Dr. Kerry Gilmore (Organic Chemistry)

Hybrid Materials Dr. Jie (Jay) He (Polymer Chemistry and Physical Chemistry)

Shape-Memory Polymers Dr. Rajeswari M. Kasi (Polymer Chemistry)

Synthesis and characterization of photoswitchable inhibitors of potassium channels Dr. Michael Kienzler (Organic and Biological Chemistry)

From the Kitchen to the Lab Dr. Nicholas Leadbeater (Inorganic Chemistry)

Supramolecular Assembly of Polypeptides into Nanomaterials Dr. Yao Lin (Polymer Chemistry)

Nanoscale Controlled Light Emitting Devices by Self-Assembly Techniques Dr. Fotios Papadimitrakopoulos (Polymer Chemistry)

Synthesis as a Tool in Glycoscience Dr. Mark W. Peczuh (Organic Chemistry)

Building Functional Nanodevices with Porous Nanocapsules Dr. Eugene Pinkhassik (Materials/Organic/Analytical/Nanoscience)

Reliability and Engineering of Molecules and Materials Next-generation Electronics. Dr. Rebecca Quardokus (physical/materials/nanoscience)

Enzyme-assembled Nanocapsules for Targeted Drug Delivery Dr. Jessica Rouge (Biological Chemistry)

Cancer Biomarker Detection by Immunoarrays Dr. James F. Rusling (Analytical, Physical Chemistry)

Catalysts, Ceramics, Batteries, and Adsorbents Dr. Steven L. Suib (Inorganic Chemistry)

Figure 1, Diagram of Oriented Fibers; Synthesis, Scanning Electron Micrograph and Coated Product.

Synthesis of molecules emitting chiral light Dr. Gaël Ung (Inorganic/organic)

Mass Spectrometry to Investigate Micro-Scale Preparation of Peptide Samples Dr. Xudong Yao (Analytical Chemistry and Biological Chemistry)

Synthesis and application of metal and semiconductor nanoparticles Dr. Jing Zhao (Analytical and Physical Chemistry)

Accounts of Chemical Research welcomes proposals for the upcoming Special Issue: “Electrosynthesis of Inorganic Materials”

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Doing away with radium’s proxies

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