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Fundamentals, synthesis, characterization and environmental applications of layered double hydroxides: a review

• Published: 26 February 2021
• Volume 19 , pages 2643–2661, ( 2021 )

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• Prabagar Samuel Jijoe 1 ,
• Shivamurthy Ravindra Yashas 1 &
• Harikaranahalli Puttaiah Shivaraju   ORCID: orcid.org/0000-0001-5125-4877 1 , 2  

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The availability of clean water and energy scarcity are rising issues in the context of rising population and industrialization, calling for advanced methods of remediation and energy production. Here, layered double hydroxides, as anionic clays, can be used and engineered as adsorbents or catalysts. Layered double hydroxides are generally highly stable, safe and recyclable. They can be filled with nanomaterials to form composites of enhanced performance. Here, we review fundamentals of layered double hydroxides, synthetic protocols, and applications to energy storage, dye degradation, organic pollutant degradation, water treatment, photoelectrochemical water splitting and carbon dioxide reduction. Composites appear competitive in terms of low-cost, tunable band-gaps and high electrical conductivity.

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All data generated or analysed during this study are included in this published article.

Abbreviations

• Layered double hydroxides

Hydrotalcite

X-ray diffraction

Fourier transform infrared

Scanning electron microscope

X-ray fluorescence

Potential of hydrogen

Magnesium–aluminium layered double hydroxide

Advanced oxidation process

Volatile organic compounds

Nickel–iron layered double hydroxide

Oxygen evolution reaction

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All the authors profusely thank the JSS Academy of Higher Education and Research, Mysuru, India to have supported the review by providing the necessary access to electronic resources.

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First and second authors have equally contributed in the material preparation, data collection, and analysis. Specifically, JSP, collected the literature and formulated the first draft of the review article. SRY, collected the data, analysed the data and contributed in writing the first draft of the articles. HPS, directed and conceptualized the review article and finally proofread the manuscript.

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Jijoe, P.S., Yashas, S.R. & Shivaraju, H.P. Fundamentals, synthesis, characterization and environmental applications of layered double hydroxides: a review. Environ Chem Lett 19 , 2643–2661 (2021). https://doi.org/10.1007/s10311-021-01200-3

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DOI : https://doi.org/10.1007/s10311-021-01200-3

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Layered double hydroxide based materials for carbon dioxide capture

This thesis discusses the development of layered double hydroxides (LDHs), layered double oxides (LDOs) and their composites for use in CO 2 capture.

Chapter One introduces LDHs, providing a background into their flexible composition and versatile application. A brief description of core@shell materials is also provided. Materials used in CO 2 capture in research and industry are discussed and compared. A background to the polyurethane (PU) curing process is als...

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Layered double hydroxide-based electrocatalysts for the oxygen evolution reaction: identification and tailoring of active sites, and superaerophobic nanoarray electrode assembly.

* Corresponding authors

a State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, China E-mail: [email protected] , [email protected]

b Department of Chemical Engineering and Biotechnology, University of Cambridge, Cambridge, UK

c Department of Chemical Engineering, Loughborough University, Loughborough, Leicestershire, UK E-mail: [email protected]

The electrocatalytic oxygen evolution reaction (OER) is a critical half-cell reaction for hydrogen production via water electrolysis. However, the practical OER suffers from sluggish kinetics and thus requires efficient electrocatalysts. Transition metal-based layered double hydroxides (LDHs) represent one of the most active classes of OER catalysts. An in-depth understanding of the activity of LDH based electrocatalysts can promote further rational design and active site regulation of high-performance electrocatalysts. In this review, the fundamental understanding of the structural characteristics of LDHs is demonstrated first, then comparisons and in-depth discussions of recent advances in LDHs as highly active OER catalysts in alkaline media are offered, which include both experimental and computational methods. On top of the active site identification and structural characterization of LDHs on an atomic scale, strategies to promote the OER activity are summarised, including doping, intercalation and defect-making. Furthermore, the concept of superaerophobicity, which has a profound impact on the performance of gas evolution electrodes, is explored to enhance LDHs and their derivatives for a large scale OER. In addition, certain operating standards for OER measurements are proposed to avoid inconsistency in evaluating the OER activity of LDHs. Finally, several key challenges in using LDHs as anode materials for large scale water splitting, such as the issue of stability and the adoption of membrane–electrode-assembly based electrolysers, are emphasized to shed light on future research directions.

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Iqbal, Muhammad Ahsan. "Layered double hydroxide based smart protective coating systems." Doctoral thesis, Università degli studi di Trento, 2021. http://hdl.handle.net/11572/302211.

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Brister, Fang Wei. "Layered Double Hydroxides: Synthesis, Characterization, and Interaction of Mg-Al Systems with Intercalated Tetracyanonickelate(II)." Thesis, University of North Texas, 2004. https://digital.library.unt.edu/ark:/67531/metadc4636/.

Djebbi, Mohamed Amine. "Les Hydroxydes Doubles Lamellaires au coeur de la biotechnologie : évaluation des applications médicales et environnementales." Thesis, Lyon, 2017. http://www.theses.fr/2017LYSE1049/document.

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Thyveetil, Mary-Ann. "Large-scale simulations of layered double hydroxide nanocomposite materials." Thesis, University College London (University of London), 2008. http://discovery.ucl.ac.uk/16745/.

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Feng, Yongjun. "Formation and properties of second-stage layered double hydroxide materials." Phd thesis, Université Blaise Pascal - Clermont-Ferrand II, 2006. http://tel.archives-ouvertes.fr/tel-00717376.

Nhlapo, N. S. (Nontete Suzan). "Intercalation of fatty acids into layered double hydroxides." Diss., University of Pretoria, 2008. http://hdl.handle.net/2263/28361.

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Ogbomo, Sunny Minister D'Souza Nandika Anne. "Processing, structure property relationships in polymer layer double hydroxide multifunctional nanocomposites." [Denton, Tex.] : University of North Texas, 2009. http://digital.library.unt.edu/ark:/67531/metadc12174.

Costa, Francis Reny. "Mg-Al Layered Double Hydroxide: A Potential Nanofiller and Flame-Retardant for Polyethylene." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2007. http://nbn-resolving.de/urn:nbn:de:swb:14-1195481811992-27563.

Ashekuzzaman, S. H. "Removal of phosphorus and arsenic oxyanions from water using layered double hydroxide adsorbent." Thesis, Glasgow Caledonian University, 2016. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.726751.

Wongariyakawee, Anchalee. "Novel layered double hydroxide chemistry for application in cement and other building materials." Thesis, University of Oxford, 2013. http://ora.ox.ac.uk/objects/uuid:3670c777-c860-43a8-9cdc-5a7d2c87b71b.

Kosuri, Divya. "Polyethylene-layered double hydroxide and montmorillonite nanocomposites: Thermal, mechanical and flame retardance properties." Thesis, University of North Texas, 2008. https://digital.library.unt.edu/ark:/67531/metadc6087/.

Carlino, Simon. "An investigation into some of the properties of a hydrotalcite-like layered double hydroxide." Thesis, University of Reading, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.387022.

Weir, Mark Robert. "Synthesis, characterization and catalytic testing of layered double hydroxide materials pillared by heteropoly oxometalate anions." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp02/NQ34709.pdf.

Baki, Musa. "Molecular simulation, application, synthesis and characterization of layered double hydroxide in search of anionic clays." To access this resource online via ProQuest Dissertations and Theses @ UTEP, 2008. http://0-proquest.umi.com.lib.utep.edu/login?COPT=REJTPTU0YmImSU5UPTAmVkVSPTI=&clientId=2515.

Torres, Dorante Luis Omar. "Evaluation of a layered double hydroxide (LDH) mineral as a long-term nitrate exchanger in soil." Göttingen Cuvillier, 2007. http://d-nb.info/985618248/04.

Clark, Ian. "Continuous synthesis and characterisation of layered double hydroxide nanomaterials for their application for dye wastewater remediation." Thesis, University of Nottingham, 2018. http://eprints.nottingham.ac.uk/52758/.

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Moyo, Lumbidzani. "Fatty acid intercalated layered double hydroxides as additives for Jojoba oil and polymer matrices." Thesis, University of Pretoria, 2012. http://hdl.handle.net/2263/25462.

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Lima, Paulo DemÃtrios da Silva. "Textural properties study of Mg-Al layered double hydroxide with different molar ratios and upon hydrothermal treatments." Universidade Federal do CearÃ, 2014. http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=13527.

Lima, Paulo Demétrios da Silva. "Textural properties study of Mg-Al layered double hydroxide with different molar ratios and upon hydrothermal treatments." reponame:Repositório Institucional da UFC, 2014. http://www.repositorio.ufc.br/handle/riufc/10730.

Stimpfling, Thomas. "Modified layered double hydroxide (LDH) platelets as corrosion inhibitors reservoirs dispersed into coating for aluminun alloy 2024." Thesis, Clermont-Ferrand 2, 2011. http://www.theses.fr/2011CLF22169.

Ko, Sae Bom. "Identification of active agents for tetrachloroethylene degradation in Portland cement slurry containing ferrous iron." Texas A&M University, 2003. http://hdl.handle.net/1969.1/3861.

Ogbomo, Sunny Minister. "Processing, structure property relationships in polymer layer double hydroxide multifunctional nanocomposites." Thesis, University of North Texas, 2009. https://digital.library.unt.edu/ark:/67531/metadc12174/.

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Phillips, Justin. "Dextrin nanocomposites and deep eutectic solvents as matrices for solid dosage forms." Diss., University of Pretoria, 2020. http://hdl.handle.net/2263/81724.

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